耐油橡膠密封氫化丁氫值得信賴上海君宜化工供應(yīng)-b2b網(wǎng)站_b2b電子商務(wù)平臺【買產(chǎn)品】-上?？谄蚴称酚邢薰?/title><meta name="description" content="均相配位催化劑目前常見的有三種:鈀催化劑、銠催化劑和銥催化劑,鈀型催化劑對水和空氣穩(wěn)定,貯運(yùn)方便,可反復(fù)回收利用,但活性和選擇性差;銥型催化劑氫化NBR具有非常高的活性和選擇性，耐油橡膠密封氫化丁氫,已成為HNBR開發(fā)的熱點(diǎn)之一。銠型催化劑"><meta name="keywords" content="耐油橡膠密封氫化丁氫"><link rel="canonical" href="http://www.cdcfah.com/"/><meta name="applicable-device" content="pc"><link rel="shortcut icon" href="/static/new_net_01/images/favicon.ico"><link rel="stylesheet" href="/static/new_net_01/css/slick.css" /><link rel="stylesheet" href="/static/new_net_01/css/addnew.css"><link rel="stylesheet" href="/static/new_net_01/css/sidenav.css"><link rel="stylesheet" href="/static/new_net_01/css/style.css" /><link rel="stylesheet" href="/static/new_net_01/css/tab.css"><link rel="stylesheet" href="/static/new_net_01/css/404.css"> <meta name="baidu-site-verification" content="OBVzrC9aaQ" /> <meta http-equiv="Cache-Control" content="no-transform" /> <meta 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src="http://tyunfile.71360.com/UploadFile/junyi/637206634828496094/1580039.jpg" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div><div id="s4k0csw" class="smallimg"><div><p class="pic"><img src="http://tyunfile.71360.com/UploadFile/junyi/637206634828496094/1580039.jpg" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div></div><div id="kmuo062" class="content"><p><span>需求數(shù)量：</span>0</p><p><span>價格要求：</span>面議</p><p><span>所在地：</span>上海市</p><p><span>包裝要求：</span><span style="color: #f30;"></span></p><p><span>產(chǎn)品關(guān)鍵詞：</span>耐油橡膠密封氫化丁氫</p><p><span>***更新：</span>2020-06-05 03:07:26</p><p><span id="click" >瀏覽次數(shù)：0次</span></p><a rel="nofollow" class="button">聯(lián)系我們</a></div></div><div id="wmagswe" class="rightbox"><h3>公司基本資料信息</h3><p style="border:0;"><a rel="nofollow">上海君宜化工銷售中心（有限合伙）</a></p><p><span>聯(lián)系人：</span>蘇剛</p><p><span>郵箱: </span>sg@estrongchem.com</p><p><span>電話: </span>13524989551</p><p><span>傳真: </span>021_60823996 </p><p><span>網(wǎng)址: </span></p><p><span>手機(jī): </span>021-60826029</p><p><span>地址: </span>上海市浦東新區(qū)五星路676弄萬科御河10棟</p><p>[當(dāng)前離線] <a rel="nofollow"> [加為商友] </a><a rel="nofollow"> [發(fā)送信件] </a></p></div></div><div id="mucsgeu" class="page-proshow02"><p class="title">詳細(xì)說明</p><div id="qssismu" class="box"><p><p style="text-indent:25px">均相配位催化劑目前常見的有三種:鈀催化劑、銠催化劑和銥催化劑,鈀型催化劑對水和空氣穩(wěn)定,貯運(yùn)方便,可反復(fù)回收利用,但活性和選擇性差;銥型催化劑氫化NBR具有非常高的活性和選擇性，耐油橡膠密封氫化丁氫,已成為HNBR開發(fā)的熱點(diǎn)之一。銠型催化劑具有比較高的活性和選擇性,RhH(PPh3)3型氫化銠催化劑可在溶液或乳液中對NBR進(jìn)行催化加氫,反應(yīng)所用溶劑為苯,溫度為80～160℃,氫壓為0.05～3MPa,時間2～10小時。為使催化劑穩(wěn)定還需加入PPh3,催化劑和PPh3的用量分別為0，耐油橡膠密封氫化丁氫.05%～20%、l%～25%(以NBR為基準(zhǔn)),兩者質(zhì)量比為0，耐油橡膠密封氫化丁氫.6/1～20/1。該催化體系具有高活性和選擇性,氫化率比較低為95%。但銠資源緊張,價值昂貴,大規(guī)模生產(chǎn)應(yīng)回收利用,有人用三氨基硅烷吸收了HNBR中81%的殘余銠。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="耐油橡膠密封氫化丁氫" src="http://tyunfile.71360.com/UploadFile/junyi/637206634828496094/1580039.jpg"></div><p style="text-indent:25px">HNBR在保持NBR原有的優(yōu)異的耐油性的同時，又獲得了非常好的耐熱性(耐150℃高溫)、耐臭氧性，其運(yùn)用領(lǐng)域已突破了NBR的傳統(tǒng)領(lǐng)域，使得氯化聚乙烯、氯磺化聚乙烯等特種橡膠也受到一定的沖擊。從經(jīng)濟(jì)角度看，HNBR銷售價暫時還較貴，但還是比氟橡膠低得多。同時，由于HNBR的剛度低，工藝性能好，密度低，可以加入更多的填料，而且HNBR制品單位體積只有氟橡膠的一半，所以，它將成為氟橡膠等特種彈性體的代用品。雖然，HNBR在國外已生產(chǎn)多年，其應(yīng)用領(lǐng)域不斷擴(kuò)大,而在國內(nèi)尚屬空白，我們應(yīng)不失時機(jī)地開發(fā)HNBR。據(jù)初步了解，我國大慶、勝利油田有2000余口二期井需用潛油泵在井深2000米，溫度140℃左右下抽油，如用NBR的錠子，使用周期*有幾個月甚至更短，使用周期可達(dá)一年以上。我國南京橡膠制品一廠每年就需HNBR30余噸。在HNBR制造中，NBR的催化加氫技術(shù)是關(guān)鍵，溶液加氫NBR生產(chǎn)技術(shù)條件苛刻，蘭化公司已在進(jìn)行這項研究工作，由于銠回收率低，成本相對較高。水溶性兩相催化劑加氫及加氫甲酰化的研究正是著眼于貴金屬催化劑的分離回收及循環(huán)使用，一旦能使這類催化劑的應(yīng)用擴(kuò)大到高分子的加氫上，就可以用它們來進(jìn)行NBR的氫化，我們已合成了兩個水溶性膦配體，正在進(jìn)行這方面的嘗試</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="耐油橡膠密封氫化丁氫" src="http://tyunfile.71360.com/UploadFile/junyi/637206634826894531/5782602.jpg"></div><p> 早在21世紀(jì)初期，全球HNBR已在NBR市場中占有5～10%的份額，保守地估計HNBR在國內(nèi)的市場用量約為1.5萬噸左右，可見HNBR的市場地位日趨重要。由于生產(chǎn)HNBR使用的催化劑價格昂貴、關(guān)鍵生產(chǎn)技術(shù)難度大，目前在世界范圍內(nèi)，產(chǎn)品上市的只有瑞翁（ZEON）公司、阿朗新科（ARLANXEO）公司和贊南科技（上海）有限公司（Zannan Scitech Co.,Ltd.）, 總產(chǎn)能大約為2.5~3萬噸/年。市場上的HNBR產(chǎn)品主要來自于上述三家公司公司，值得關(guān)注的是國產(chǎn)HNBR—詹博特®氫化丁腈橡膠（Zhanber ® HNBR）異軍突起，順利地進(jìn)入了在國內(nèi)外的HNBR市場上，獲得了市場的認(rèn)可。 </p> <p> 全球氫化丁腈橡膠生產(chǎn)現(xiàn)狀，從HNBR的工業(yè)化生產(chǎn)發(fā)展歷程來看，HNBR生產(chǎn)技術(shù)的優(yōu)勢主要就體現(xiàn)在其生產(chǎn)過程所用催化劑體系，即：催化加氫活性和選擇性、催化劑回收、產(chǎn)品后處理等關(guān)鍵技術(shù)的先進(jìn)性上。上世紀(jì)九十年代，全世界可工業(yè)化生產(chǎn)HNBR的廠家為德國拜耳（Bayer）公司、日本瑞翁 (Zeon)公司和加拿大寶蘭山（Polysar）公司等三家公司，他們都是在解決了催化加氫、催化劑回收以及產(chǎn)品后處理等關(guān)鍵工藝技術(shù)問題后，才實(shí)現(xiàn)了工業(yè)化生產(chǎn)的，當(dāng)時全球的HNBR產(chǎn)能和產(chǎn)量基本上在1萬噸/年左右。 </p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="耐油橡膠密封氫化丁氫" src="http://tyunfile.71360.com/UpLoadFile/junyi/2019/9/637038073818719493/6370380738187194934932907.jpg"></div></p><br /><p>文章來源地址: http://www.cdcfah.com/cp/149180.html</p></div></div></div></div></div><div id="ua68smg" class="page-right twoColRt"><div id="co8euis" class="box01 margin10 clearfix"><h3><a href="http://www.cdcfah.com/cp/">猜你喜歡</a></h3><div id="isuiyag" class="recomPic likePro"><a href="http://www.cdcfah.com/cp/814588.html"><div><img src="http://tyunfile.71360.com/UpLoadFile/2019/11/1/14/637082168864691056_lgpj_5374157.jpg" alt="福建ZF配件哪家強(qiáng) 信息推薦自業(yè)物資供應(yīng)" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></div><p>福建ZF配件哪家強(qiáng) 信息推薦自業(yè)物資供應(yīng)</p></a></div><div id="yqegk4y" class="recomPic likePro"><a href="http://www.cdcfah.com/cp/846569.html"><div><img src="https://tyunfile.71360.com/WaterMark/UploadFile/nbzxsw/637298235378037109/764794.png" alt="寧波寧海直接考A2有幾個科目真誠推薦寧波助學(xué)商務(wù)信息咨詢供應(yīng)" class="vcenter" 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