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class="content"><p><span>需求數(shù)量：</span>0</p><p><span>價格要求：</span>面議</p><p><span>所在地：</span>山東省</p><p><span>包裝要求：</span><span style="color: #f30;"></span></p><p><span>產(chǎn)品關(guān)鍵詞：</span>濟(jì)寧丙烯酸酯壓敏膠生產(chǎn)公司</p><p><span>***更新：</span>2020-06-10 10:20:02</p><p><span id="click" >瀏覽次數(shù)：0次</span></p><a rel="nofollow" class="button">聯(lián)系我們</a></div></div><div id="q4iwk42" class="rightbox"><h3>公司基本資料信息</h3><p style="border:0;"><a rel="nofollow">臨沂金港精細(xì)化工有限公司</a></p><p><span>聯(lián)系人：</span>姚其營</p><p><span>郵箱: </span>jingangjiaozhan@163.com</p><p><span>電話: </span>18653987178</p><p><span>傳真: </span>0539_7858566</p><p><span>網(wǎng)址: </span></p><p><span>手機(jī): </span>0539-7858566</p><p><span>地址: </span>臨港經(jīng)濟(jì)開發(fā)區(qū)團(tuán)林鎮(zhèn)</p><p>[當(dāng)前離線] <a rel="nofollow"> [加為商友] </a><a rel="nofollow"> [發(fā)送信件] </a></p></div></div><div id="gkiq4ca" class="page-proshow02"><p class="title">詳細(xì)說明</p><div id="iyoemao" class="box"><p><p> 壓敏膠粘劑性能測定要求 </p> <p> 根據(jù)使用方法和領(lǐng)域的不同，乳液壓敏膠有不同的性能測試要求。但基本的性能可以大致分為兩類：乳液性能和壓敏膠力學(xué)性能。其中乳液性能是指乳液本身的一些基本性能，如：固含量、pH值、稀釋穩(wěn)定性、機(jī)械穩(wěn)定性、粘度、pH穩(wěn)定性等等。力學(xué)性能是從膠粘劑使用來評價，包括：初粘性、持粘性、180°剝離強(qiáng)度等等，好的壓敏膠應(yīng)該很好地平衡這三大力學(xué)性能。另外還包括施工性能、著色性能等等。 </p> <p> 壓敏膠粘劑步驟方法措施 </p> <p> 試驗(yàn)準(zhǔn)備由于該試驗(yàn)所合成的壓敏膠，在不同原料配比得情況下可以合成性能不同得壓敏膠。應(yīng)為軟單體、硬單體、改性功能單體它們在組成上相互依存相互制約。要平衡壓敏膠的粘附作用、內(nèi)聚力，濟(jì)寧丙烯酸酯壓敏膠生產(chǎn)公司、粘接性能以及耐水性、耐候性、耐溶劑性就必須先確定各種原料得用量比。查閱相關(guān)文獻(xiàn)知：甲基丙烯酸甲酯與丙烯酸丁酯的比例應(yīng)為1：70；丙烯酸羥乙酯與丙烯酸丁酯的比例應(yīng)為1：60；過liu酸銨引發(fā)劑用量定為單體量的0.5%；乳化劑用量達(dá)到CMC值為易為單體的1.5%；保護(hù)膠定位單體量的2.2%，濟(jì)寧丙烯酸酯壓敏膠生產(chǎn)公司。由此確定其油水比為54：46，濟(jì)寧丙烯酸酯壓敏膠生產(chǎn)公司.這樣所制得的產(chǎn)品性能比較平均良好。 </p> <p> 想要了解更多關(guān)于壓敏膠的知識，歡迎咨詢金港精細(xì)化工。 </p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="濟(jì)寧丙烯酸酯壓敏膠生產(chǎn)公司" src="http://tyunfile.71360.com/UploadFile/lyjgjxhgyxgs/637143715341425781/8331891.jpg"></div><p> 相對分子質(zhì)量及其分布對壓敏膠性能的影響 </p> <p> 共聚物的相對分子質(zhì)量對它們的力學(xué)性能和膠粘性能有很大影響，低相對分子質(zhì)量共聚物制成的壓敏膠，雖然初粘力有時可能不錯，但剝離強(qiáng)度和持粘力一般都不高，一個好的壓敏膠其持粘力隨相對分子質(zhì)量增加而迅速提高，初粘力和剝離強(qiáng)度則下降到一個穩(wěn)定水平，剝離出現(xiàn)穩(wěn)定的界面破壞。因此，制備丙烯酸酯壓敏膠時必須將共聚物的相對分子質(zhì)量控制在一定的范圍內(nèi)。共聚物組成和結(jié)構(gòu)不同，相對分子質(zhì)量的較好范圍也不相同。 </p> <p> 相對分子質(zhì)量分布對壓敏膠的性能也有影響，一般來說，高相對分子質(zhì)量的部分決定了壓敏膠的持粘力，低相對分子質(zhì)量成分則影響初粘力和剝離強(qiáng)度。在同樣的情況下，相對分子質(zhì)量分布較寬的共聚物膠粘劑更容易做到壓敏膠三大性能的平衡。實(shí)際表明，在相對分子質(zhì)量較高的交聯(lián)型丙烯酸酯壓敏膠中，混入少量較低相對分子質(zhì)量的非交聯(lián)型丙烯酸酯共聚物，使用權(quán)相對分子質(zhì)量分布變寬，可以在保持較好持粘力的情況下在極大的提高初粘力和剝離強(qiáng)度。 </p> <p> 想了解更多資訊，歡迎關(guān)注臨沂金港精細(xì)化工。 </p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="濟(jì)寧丙烯酸酯壓敏膠生產(chǎn)公司" src="http://tyunfile.71360.com/UploadFile/lyjgjxhgyxgs/637143714227998047/1818969.jpg"></div><p> 丙烯酸酯共聚物的交聯(lián) </p> <p> 要使丙烯酯壓敏膠有較好的持粘力，必須使共聚物有較高的重均相對分子質(zhì)量，然而這樣的膠粘劑，尤其是溶液型壓敏膠，往往會在粘度太大而難以涂布。若將相對分子質(zhì)量不太高因而粘度也不太大的共聚物在涂布時或涂布后進(jìn)行適當(dāng)?shù)慕宦?lián)，便可解決性能和工芤的矛盾。同時，交聯(lián)可以改善壓敏膠的耐高溫性能、耐溶劑性和耐老化性能，因此丙烯酸酯共聚物的交聯(lián)具有很重要的實(shí)際價值。 </p> <p> 具體的交聯(lián)方法可歸納為如下5種： </p> <p> (1) 利用活潑羥甲基的縮合反應(yīng)而交聯(lián)。 </p> <p> (2) 利用異氰酸酯反應(yīng)而交聯(lián) 含羥基、羧基和仲胺基的丙烯酸酯共聚物，能夠用多異氰酸酯及其加成進(jìn)行交聯(lián)。 </p> <p> (3) 利用不著環(huán)氧基反應(yīng)交聯(lián) 含胺基、羥基和或羧基的丙烯酸酯共聚物可用環(huán)愧疚樹脂或多環(huán)愧疚化合物交聯(lián)，而含環(huán)氧基的丙烯酸酯共聚則可用多元胺或多元酸酐等化合物交聯(lián)。 </p> <p> (4) 利用烷氧基金屬化合物的反應(yīng)而交聯(lián) 四丁氧基鈦、四異丙氧基鈦、三異丙氧基鋁等烷氧基金屬化合物能在室溫或較低溫度下與丙烯酸酯共聚物的羧基或羥基很快發(fā)生酯化或烷氧基交換反應(yīng)而交聯(lián)。 </p> <p> (5) 離子型交聯(lián) 用金屬的鹽類，如鋅、鉛、鈉、鈷等多價或單價金屬的醋酸、辛酸、環(huán)烷酸或月桂酸等有機(jī)酸的鹽與含羧基的丙烯酸酯共聚物交聯(lián)。 </p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="濟(jì)寧丙烯酸酯壓敏膠生產(chǎn)公司" src="http://tyunfile.71360.com/UploadFile/lyjgjxhgyxgs/637143715261289062/1231987.jpg"></div></p><br /><p>文章來源地址: 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