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[發(fā)送信件] </a></p></div></div><div id="lqxzgse" class="page-proshow02"><p class="title">詳細說明</p><div id="pegykhj" class="box"><p><p style="text-indent:25px">本文對聚乳酸的合成方法及近年來聚乳酸基納米復(fù)合材料的研究進展進行了綜述,創(chuàng)新性地提出以L-乳酸和酸性硅溶膠(aSS)為原料的原位熔融縮聚法,制備了SiO_2含量為3.5％-19.1％的聚乳酸納米復(fù)合材料,并對聚乳酸/SiO_2納米復(fù)合材料的結(jié)構(gòu)、透光率、熱性能和結(jié)晶性進行了較深入的研究。在L-乳酸熔融縮聚過程中,隨著聚乳酸分子量的提高，湖北全生物降解膜廠家,體系的極性發(fā)生明顯變化:由酸性單體的強極性/親水性變?yōu)榫廴樗岬娜鯓O性/親油性。本文選擇酸性硅溶膠(pH=2.5)與L-乳酸單體水溶液直接混合進行原位分散，湖北全生物降解膜廠家?？梢耘cL-乳酸單體(LLA)和乳酸齊聚物(OLLA)的羧基發(fā)生縮合反應(yīng),使OLLA接枝到SiO_2表面,隨著接枝反應(yīng)的進行以及g-OLLA鏈的增長，湖北全生物降解膜廠家,無機相的極性也逐漸減弱,因而無機相表面也發(fā)生與有機相同步的極性變化；另一方面,g-OLLA在SiO_2粒子表面取代擴散雙電層形成保護層,提供了位阻效應(yīng)。二者均起到了促進SiO_2粒子分散穩(wěn)定的作用,因此**終能得到SiO_2粒子在聚乳酸基體中納米級分散的聚乳酸/SiO_2納米復(fù)合材料。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="湖北全生物降解膜廠家" src="https://tyunfile.71360.com/UploadFile/huixinghb/637254079272470703/3522374.jpg"></div><p> 產(chǎn)品進入降解期，意味著其基本功能已經(jīng)執(zhí)行完畢，開始步入消亡，在此階段，可降解地膜會逐步出現(xiàn)魚眼裂口、小裂口、大裂口、碎裂、消失等幾個步驟，其本質(zhì)是分子量逐漸減小，**終被土壤微生物吸收利用，轉(zhuǎn)化為水、二氧化碳和土壤有機質(zhì)。 </p> <p> 就這樣一款產(chǎn)品經(jīng)歷了從無到有再到無的循環(huán)，進入生態(tài)圈，實現(xiàn)了從哪里來到哪里去的循環(huán)。 <p> 產(chǎn)品進入降解期，意味著其基本功能已經(jīng)執(zhí)行完畢，開始步入消亡，在此階段，可降解地膜會逐步出現(xiàn)魚眼裂口、小裂口、大裂口、碎裂、消失等幾個步驟，其本質(zhì)是分子量逐漸減小，**終被土壤微生物吸收利用，轉(zhuǎn)化為水、二氧化碳和土壤有機質(zhì)。 </p> <p> 就這樣一款產(chǎn)品經(jīng)歷了從無到有再到無的循環(huán)，進入生態(tài)圈，實現(xiàn)了從哪里來到哪里去的循環(huán)。 </p> </p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="湖北全生物降解膜廠家" src="https://tyunfile.71360.com/UploadFile/huixinghb/637254079272744141/2916292.jpg"></div><p style="text-indent:25px">本文對聚乳酸的合成方法及近年來聚乳酸基納米復(fù)合材料的研究進展進行了綜述,創(chuàng)新性熔融縮聚法,制備了SiO_2含量為3.5％-19.1％的聚乳酸納米復(fù)合材料,并對聚乳酸/SiO_2納米復(fù)合材料的結(jié)構(gòu)、透光率、熱性能和結(jié)晶性進行了較深入的研究。在L-乳酸熔融縮聚過程中,隨著聚乳酸分子量的提高,體系的極性發(fā)生明顯變化:由酸性單體的強極性/親水性變?yōu)榫廴樗岬娜鯓O性/親油性。本文選擇酸性硅溶膠(pH=2.5)與L-乳酸單體水溶液直接混合進行原位分散。由于二者均為強酸性、強極性,且均為水分散液,確保了SiO_2粒子的分散穩(wěn)定,且方便地實現(xiàn)了SiO_2粒子在L-乳酸單體中的均勻分散。在縮聚過程中,一方面有機相由于聚乳酸鏈的增長,使極性變?nèi)?而無機相SiO_2粒子表面分布有活性高的硅羥基,可以與L-乳酸單體(LLA)和乳酸齊聚物(OLLA)的羧基發(fā)生縮合反應(yīng),使OLLA接枝到SiO_2表面,隨著接枝反應(yīng)的進行以及g-OLLA鏈的增長,無機相的極性也逐漸減弱,因而無機相表面也發(fā)生與有機相同步的極性變化；另一方面,g-OLLA在SiO_2粒子表面取代擴散雙電層形成保護層,提供了位阻效應(yīng)。二者均起到了促進SiO_2粒子分散穩(wěn)定的作用,因此**終能得到SiO_2粒子在聚乳酸基體中納米級分散的聚乳酸/SiO_2納米復(fù)合材料。</p></p><br /><p>文章來源地址: http://www.cdcfah.com/cp/327755.html</p></div></div></div></div></div><div id="etldfx8" class="page-right twoColRt"><div id="lk7kzl2" class="box01 margin10 clearfix"><h3><a href="http://www.cdcfah.com/cp/">猜你喜歡</a></h3><div id="dxzbolc" class="recomPic likePro"><a 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