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tcPro"><section class="home-main container clearfix"><div id="bcyfmvr" class="twoCol"><div id="mldkheg" class="page-proshow clearfix"><p class="current"> 當前位置:<a href="http://www.cdcfah.com/">首頁?<a href="http://www.cdcfah.com/cp/">產(chǎn)品供應(yīng)</a>?<a href="http://www.cdcfah.com/cp/first-_huagong/">化工</a>?<a href="http://www.cdcfah.com/cp/second-huagong_cysbqv/">儲運設(shè)備</a>?<a href="http://www.cdcfah.com/cp/third-cysbqv_chuguan/">儲罐</a>?吉林電解液桶促銷蘇州圣思瑞包裝容器供應(yīng)</p><div id="mvszrda" class="leftbox clearfix"><h1>吉林電解液桶促銷蘇州圣思瑞包裝容器供應(yīng)</h1><div id="3f87r5d" class="proBig"><div id="ti3w7ik" class="bigimg"><div><p class="pic"><img src="https://tyunfile.71360.com/UploadFile/szssrb/637250564256884766/3650285.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div><div id="ap4ztkm" class="smallimg"><div><p class="pic"><img src="https://tyunfile.71360.com/UploadFile/szssrb/637250564256884766/3650285.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div></div><div id="pzyf8ax" class="content"><p><span>需求數(shù)量：</span>0</p><p><span>價格要求：</span>面議</p><p><span>所在地：</span>江蘇省</p><p><span>包裝要求：</span><span style="color: #f30;"></span></p><p><span>產(chǎn)品關(guān)鍵詞：</span>吉林電解液桶促銷,電解液桶</p><p><span>***更新：</span>2021-01-08 03:06:04</p><p><span id="click" >瀏覽次數(shù)：0次</span></p><a rel="nofollow" class="button">聯(lián)系我們</a></div></div><div id="3y4npm7" class="rightbox"><h3>公司基本資料信息</h3><p style="border:0;"><a rel="nofollow">蘇州圣思瑞包裝容器有限公司</a></p><p><span>聯(lián)系人：</span>邵先生</p><p><span>郵箱: </span>szdjyt@126.com</p><p><span>電話: </span>18362765789</p><p><span>傳真: </span>0512_65780567</p><p><span>網(wǎng)址: </span></p><p><span>手機: </span>0512-65780577</p><p><span>地址: </span>富元路1088號</p><p>[當前離線] <a rel="nofollow"> [加為商友] </a><a rel="nofollow"> [發(fā)送信件] </a></p></div></div><div id="sr4qdk4" class="page-proshow02"><p class="title">詳細說明</p><div id="lzy2n4x" class="box"><p><p> 所述正極膜片包括正極活性物質(zhì)、導(dǎo)電劑和粘結(jié)劑；推薦地，所述正極活性物質(zhì)為lini1-x-y-zcoxmnyalzo2、鎳錳酸鋰、鈷酸鋰、富鋰錳基固溶體或錳酸鋰，其中：0≤x≤1，0≤y≤1，0≤z≤1且0≤x+y+z≤1；更推薦地，所述正極材料為高鎳材料。本發(fā)明的鋰離子電池的負極活性物質(zhì)可選自人造石墨、包覆型天然石墨、硅碳負極、硅負極；推薦地，所述電池的形態(tài)為圓柱、鋁殼、塑殼或軟包殼體，吉林電解液桶促銷。本發(fā)明的鋰離子電池的上限截止電壓推薦為。與現(xiàn)有技術(shù)相比，本發(fā)明具有以下優(yōu)點：本發(fā)明的鋰離子電池電解液中，芳基含硫類化合物的homo能量較低，充電時易優(yōu)先于非水溶劑發(fā)生氧化反應(yīng)，氧化產(chǎn)物沉積在正極表面形成致密的cei膜，熱穩(wěn)定性好，吉林電解液桶促銷，一方面減少六氟磷酸鋰熱分解和水解產(chǎn)生的hf對正極材料的腐蝕，鈷、鎳等過渡金屬離子的溶出和在負極上的沉積，提升室溫循環(huán)性能；另一方面該鈍化膜減少活性物質(zhì)的損失和界面副反應(yīng)，防止高溫環(huán)境中溶出的過渡金屬元素對非水溶劑的催化分解和產(chǎn)氣膨脹。含硼鋰鹽的lumo能量低，在充放電中在石墨表面發(fā)生還原反應(yīng)參與有保護作用的sei膜形成，非水溶劑的進一步分解，穩(wěn)定石墨負極/電解液表面，吉林電解液桶促銷，提高循環(huán)可逆容量。負極成膜添加劑先于非水溶劑發(fā)生還原分解。不銹鋼電解液生產(chǎn)廠家**名。吉林電解液桶促銷</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="吉林電解液桶促銷,電解液桶" src="https://tyunfile.71360.com/UploadFile/szssrb/637250564256884766/3650285.png"></div><p> 電解液桶內(nèi)充填的氣體，以前**早用的是高純氬氣，因為氬氣不會與任何成分反應(yīng)，十分惰性。后來的廠家常用氮氣代替氬氣，其成本就低得多了，問題也不大。雖然氮氣與鋰或碳化鋰會反應(yīng)，但在電解液中溶解有限，不太會帶入到電池體系中，其副作用十分有限，因此用氮氣就十分普遍了。一般廠家都會選擇液氮，其水分含量非常低。峰對分別對應(yīng)于鋰離子同SiO2結(jié)構(gòu)作用形成Li2Si2O5和單晶硅，以及鋰離子同單晶硅作用形成LixSi合金的過稱。圖19（d）是無定形一氧化硅材料第二次充放電循環(huán)的容量微分曲線。由圖可知，無定形一氧化硅材料在第二次放電過程中存在兩個電勢分別為，與之對應(yīng)的是電勢為V的兩個氧化峰。一氧化硅負極材料的結(jié)構(gòu)包含[SiSi4]微區(qū)和SiO2微區(qū)，這兩對氧化還原峰對應(yīng)的是這兩種微區(qū)結(jié)構(gòu)同鋰離子的作用。圖19幾種負極材料（a）無定形炭、（b）硅、（c）二氧化硅、（c）一氧化硅材料前兩次充放電循環(huán)的容量微分曲線來源：電動網(wǎng)作者：mikoWoo本文地址：/kol/71153返回電動網(wǎng)首頁>本文由電動網(wǎng)大牛說作者撰寫，他們?yōu)楸疚牡恼鎸嵭院椭辛⑿载撠?，觀點*個人，不電動網(wǎng)。本文版權(quán)歸原創(chuàng)作者和電動網(wǎng)（）所有，如需轉(zhuǎn)載需得到雙方授權(quán)，同時務(wù)必注明來源和作者。湖南電解液桶直供拉電解液的不銹鋼車桶。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="吉林電解液桶促銷,電解液桶" src="https://tyunfile.71360.com/UploadFile/szssrb/637250564287441406/8353599.png"></div><p> 更推薦碳原子數(shù)為1～4的亞烷基。作為烷基的實例，具體可以舉出：亞甲基、亞乙基、亞丙基、亞異丙基、亞丁基、亞異丁基、亞仲丁基、亞戊基、亞己基。碳原子數(shù)為2～12的亞烯基為直鏈或支鏈亞烯基，烯基中雙鍵的個數(shù)推薦為1個。所述亞烯基中碳原子數(shù)推薦的下限值為3，4，5，6，推薦的上限值為4，5，6，7，8，9，10。推薦地，選擇碳原子數(shù)為2～8的亞烯基；更推薦碳原子數(shù)為2～6的亞烯基。作為亞烯基的實例，具體可以舉出：亞乙烯基、亞烯丙基、亞異丙烯基、亞烯丁基、亞烯戊基。鹵素選自氟、氯、溴。作為本申請電解液的一種改進，本申請sei成膜添加劑在電解液中的質(zhì)量百分含量為％～30％。推薦地，sei成膜添加劑在電解液中的質(zhì)量百分含量范圍的上限任選自30％、28％、26％、24％、22％、20％、16％、14％、10％，下限任選自％、％、％、％、1％、2％、5％、8％。更進一步推薦地，sei成膜添加在電解液中的百分含量為％～2％。作為本申請電解液的一種改進，本申請的電解液為非水電解液，有機溶劑選自碳酸乙烯酯(ec)、碳酸丙烯脂(pc)、碳酸丁烯酯、氟代碳酸乙烯酯、碳酸甲乙酯、碳酸二甲酯、碳酸二乙酯(dec)、碳酸二丙酯、碳酸甲丙酯、碳酸乙丙酯、1,4-丁內(nèi)酯。</p><p> 通過調(diào)整sei膜組成，減小sei膜阻抗，提高高鎳鋰電池的循環(huán)性能和低溫循環(huán)性能。因此同時添加了含硼鋰鹽和負極成膜添加劑的對比例2的電池常溫循環(huán)1000周容量保持率提高了約30％。但對比例2中，熱態(tài)膨脹率達％，說明這兩種添加劑不能高溫產(chǎn)氣，電池的高溫存儲性能不能得到保證。結(jié)合實施例1～18，芳基含硫類化合物的homo能量較低，充電時易優(yōu)先于溶劑發(fā)生氧化反應(yīng)，氧化產(chǎn)物沉積在正極表面形成致密的cei膜，熱穩(wěn)定性好，一方面減少六氟磷酸鋰熱分解和水解產(chǎn)生的hf對正極材料的腐蝕，鈷、鎳等過渡金屬離子的溶出和在負極上的沉積，提升室溫循環(huán)性能；另一方面該鈍化膜減少活性物質(zhì)的損失和界面副反應(yīng)，防止高溫環(huán)境中溶出的過渡金屬元素對溶劑的催化分解和產(chǎn)氣膨脹。與只添加了含硼鋰鹽和負極成膜添加劑的對比例2相比，實施例1～18也體現(xiàn)出明顯的性能優(yōu)勢，這說明通過芳基含硫酯類化合物和含硼鋰鹽聯(lián)合作用(實施例1～18)，綜合調(diào)節(jié)正負極表面sei膜的成分，保證。對比例3-4同時添加了3種添加劑，但與實施例1～18相比，對比例3中的60℃存儲7天后的電池產(chǎn)氣，容量剩余率較小，推測芳基含硫酯類化合物添加過少，對正極保護作用不明顯。不銹鋼桶;化工桶;電解液桶;不銹鋼噸桶IBC;光阻桶。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="吉林電解液桶促銷,電解液桶" src="https://tyunfile.71360.com/UploadFile/szssrb/637250564618427734/3924273.png"></div><p> 本申請鹵代硅烷化合物選自式(ⅰ-1)至式(ⅰ-13)所述化合物中的至少一種，但不限于此。作為本申請電解液的一種改進，本申請鹵代硅烷化合物在電解液中的質(zhì)量百分含量為％～5％。當鹵代硅烷化合物的含量低于％時，不能在正負極表面形成完整而有效的cei/sei膜，從而不能有效阻止電解液與電極之間的電子轉(zhuǎn)移所引起的副反應(yīng)；而當鹵代硅烷化合物含量大于5％時，會在正陰極表面形成較厚的cei/sei膜，導(dǎo)致鋰離子遷移阻力增大，同時未成膜的硅烷化合物會在循環(huán)過程中進一步氧化，不利于循環(huán)過程中電池的正極界面穩(wěn)定性。進一步推薦地，本申請鹵代硅烷化合物在電解液中的質(zhì)量百分含量范圍的上限任選自5％、4％、3％、％、％、％，下限任選自％、％、％、％、％、％、％、％。更進一步推薦地，鹵代硅烷化合物在電解液中的百分含量為％～2％。作為本申請電解液的一種改進，sei成膜添加劑選自環(huán)狀碳酸酯化合物、環(huán)狀酯化合物、磺酸內(nèi)酯化合物、二磺酸亞甲酯化合物、腈化合物中的至少一種。作為本申請的一種改進，環(huán)狀碳酸酯化合物的結(jié)構(gòu)式如式ⅱ-1所示，r21選自取代或未取代的c1～6亞烷基、取代或未取代的c2～6亞烯基；取代基選自鹵素、c1～6烷基、c2～6烯基。電解液鋼瓶生產(chǎn)廠家。湖南電解液桶直供</p><p style="text-indent:25px">鋰電池電解液桶生產(chǎn)廠家。吉林電解液桶促銷</p><p> r2分別**地選自氫原子、氧原子、氟原子、1-4個碳的烷基、烯基、炔基、腈基、氟代烷基、氧烷基、芳基，且r1，r2中至少有一個芳基。所述芳基含硫酯類化合物更推薦為以下結(jié)構(gòu)式所示化合物中的一種或多種：作為本發(fā)明的推薦實施方式，所述含硼鋰鹽推薦雙草酸硼酸鋰(libob)、二氟草酸硼酸鋰(lidfob)、四氟硼酸鋰(libf4)、libf2(cf3)2、libf2(c2f5)2中的一種或多種。所述含硼鋰鹽更推薦為雙草酸硼酸鋰、二氟草酸硼酸鋰、四氟硼酸鋰中的一種。作為本發(fā)明的推薦實施方式，所述負極成膜添加劑推薦為vc(碳酸亞乙烯酯)、氟代碳酸乙烯酯(fec)、乙烯酯(dtd)、三(三甲基)硅烷硼酸酯(tmsb)、三(三甲基)硅烷磷酸酯(tmsp)、雙三氟甲基磺酰亞胺鋰(litfsi)、二氟磷酸鋰(lidfp)中的一種或多種。作為本發(fā)明的推薦實施方式，所述鋰鹽推薦為六氟磷酸鋰(lipf6)、六氟砷酸鋰、高氯酸鋰、四氟硼酸鋰、雙草酸硼酸鋰、三草酸磷酸鋰、二氟草酸硼酸鋰、雙氟磺酰亞胺鋰(lifsi)、雙三氟甲烷磺酰亞胺鋰(litfsi)、二氟磷酸鋰、四氟磷酸鋰和二氟雙草酸磷酸鋰中的一種或多種。作為本發(fā)明的推薦實施方式，所述鋰鹽在鋰離子電池電解液中的質(zhì)量百分含量推薦為％。吉林電解液桶促銷</p></p><br /><p>文章來源地址: http://www.cdcfah.com/cp/2749526.html</p></div></div></div></div></div><div id="vk9ewdx" class="page-right twoColRt"><div id="8s4megf" class="box01 margin10 clearfix"><h3><a href="http://www.cdcfah.com/cp/">猜你喜歡</a></h3><div id="cw9lxel" class="recomPic likePro"><a href="http://www.cdcfah.com/cp/814588.html"><div><img 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