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</a></p></div></div><div id="dj3hvjp" class="page-proshow02"><p class="title">詳細(xì)說(shuō)明</p><div id="7h5vhdb" class="box"><p><p> 它可以用作中子源。比穩(wěn)定同位素Sb輕的同位素傾向于發(fā)生β衰變，而較重的同位素更易發(fā)生β衰變。當(dāng)然也有一些例外，西安5N銻粒廢料回收。銻化合物通常分為+3價(jià)和+5價(jià)兩類(lèi)。與同主族的砷一樣，它的+5氧化態(tài)更為穩(wěn)定。氧化物與氫氧化物；三氧化二銻可由銻在空氣中燃燒制得。在氣相中，它以雙聚體SbO的形式存在，但冷凝時(shí)會(huì)形成多聚體。五氧化二銻只能用濃硝酸氧化三價(jià)銻化合物制得。銻也VV能形成混合價(jià)態(tài)化合物——四氧化二銻，其中的銻為Sb(III)和Sb(V)。與磷和砷不同的是，這些氧化物都是兩性的，它們不形成定義明確的含氧酸，而是與酸反應(yīng)形成銻鹽。作用：氫氧化物曾廣用作溶劑、滅火劑、有機(jī)物的氯化劑、香料的浸出劑、纖維的脫脂劑、糧食的蒸煮劑、藥物的萃取劑、有機(jī)溶劑、織物的干洗劑，但是由于毒性的關(guān)系現(xiàn)在甚少使用并被限制生產(chǎn)，西安5N銻粒廢料回收，很多用途也被銅鋅合金等所替代。也可用來(lái)合成三氧化二銻、尼龍7、尼龍9的單體；還可制三氯甲烷和藥物；金屬切削中用作潤(rùn)滑劑，西安5N銻粒廢料回收。鹵化物：銻能形成兩類(lèi)鹵化物——SbX和SbX。其中三鹵化物（SbF、SbCl、SbBr和SbI）的空間構(gòu)型都是三角錐形。三氟化銻可以由三氧化二銻與氫氟酸反應(yīng)制得：Sb2O3+6HF→2SbF3+3H2O；這種氟化物是路易斯酸。大約17世紀(jì)時(shí)，人們知道了銻是一種化學(xué)元素。西安5N銻粒廢料回收</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="西安5N銻粒廢料回收,銻" src="https://tyunfile.71360.com/UploadFile/scmhkj/637465972253108557/5257155.png"></div><p> 中文名銻外文名antimonystibium分子量CAS登錄號(hào)7440-36-0[2]EINECS登錄號(hào)231-146-5[2]熔點(diǎn)630℃沸點(diǎn)1635℃密度g/cm3外觀帶有銀色光澤的灰色金屬應(yīng)用滅火劑、有機(jī)物的氯化劑、香料的浸出劑、纖維的脫脂劑等安全性描述密封干燥保存危險(xiǎn)性描述銻（易制爆）化學(xué)品類(lèi)別金屬單質(zhì)化合物價(jià)態(tài)常見(jiàn)有+3、+5地殼豐度百萬(wàn)分之族氮族(VA族)周期第五周期原子序數(shù)51外面電子排布5s25p3元素符號(hào)Sb目錄1理化性質(zhì)?物理性質(zhì)?化學(xué)性質(zhì)2化合物3化學(xué)循環(huán)4生產(chǎn)5歷史6應(yīng)用?阻燃劑?合金?其他應(yīng)用7安全銻理化性質(zhì)編輯銻物理性質(zhì)蒸餾銻晶體銻是一種帶有銀色光澤的灰色金屬，其莫氏硬度為3。因此，純銻不能用于制造硬的物件：中國(guó)的貴州省曾在1931年發(fā)行銻制的硬幣，但因?yàn)殇R很容易磨損，在流通過(guò)程損失嚴(yán)重。物態(tài)固態(tài)密度（接近室溫）g·cm熔點(diǎn)時(shí)液體密度g·cm熔點(diǎn)K，°C，°F沸點(diǎn)1860K，1587°C，2889°F熔化熱·mol汽化熱kJ·mol比熱容J·mol·K蒸汽壓壓/Pa1101001k10k100k溫/K銻化學(xué)性質(zhì)銻是氮族元素（15族），電負(fù)性為。根據(jù)元素周期律，它的電負(fù)性比錫和鉍大，比碲和砷小。銻在室溫下的空氣中是穩(wěn)定的，但加熱時(shí)能與氧氣反應(yīng)生成三氧化二銻。[3]銻在一般條件下不與酸反應(yīng)。廣東5N5銻丸銻是一種帶有銀色光澤的灰色金屬，其莫氏硬度為3。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="西安5N銻粒廢料回收,銻" src="https://tyunfile.71360.com/UploadFile/scmhkj/637465973302327366/2844088.png"></div><p> 已知銻有四種同素異形體——一種穩(wěn)定的金屬銻和三種亞穩(wěn)態(tài)銻（炸開(kāi)性銻、黑銻、黃銻）。金屬銻是一種易碎的銀白色有光澤的金屬。把熔融的銻緩慢冷卻，金屬銻就會(huì)結(jié)成三方晶系的晶體，其與砷的灰色同素異形體異質(zhì)同晶。罕見(jiàn)的炸開(kāi)形狀的銻可由電解三氯化銻制得，用尖銳的器具刮擦它就會(huì)發(fā)生放熱的化學(xué)反應(yīng)，放出白煙并生成金屬銻。如果在研缽中用研杵將它磨碎，就會(huì)發(fā)生劇烈的炸開(kāi)。黑銻是由金屬銻的蒸汽急劇冷卻形成的，它的晶體結(jié)構(gòu)與紅磷和黑砷相同，在氧氣中易被氧化甚至自燃。當(dāng)溫度降到100℃時(shí)，它逐漸轉(zhuǎn)變成穩(wěn)定的晶型。黃銻是很不穩(wěn)定的一種，只能由銻化氫在-90℃下氧化而得。在這種溫度和環(huán)境光線的作用下，亞穩(wěn)態(tài)的同素異形體會(huì)轉(zhuǎn)化成更穩(wěn)定的黑銻。[4]金屬銻的結(jié)構(gòu)為層狀結(jié)構(gòu)（空間群：），而每層都包含相連的褶皺六元環(huán)結(jié)構(gòu)。很近的和次近的銻原子形成變形八面體，在相同雙層中的三個(gè)銻原子比其他三個(gè)相距略近一些。這種距離上的相對(duì)近使得金屬銻的密度達(dá)到，但層與層之間的成鍵很弱也造成它很軟且易碎。[3]同位素銻有兩種穩(wěn)定同位素，Sb的自然豐度為，而Sb的自然豐度為。銻還有35種放射性同位素，其中半衰期很長(zhǎng)的Sb為。此外，已發(fā)現(xiàn)了29種亞穩(wěn)態(tài)。</p><p> 第三版)國(guó)家環(huán)保局編5-Br-PADAP光度法《空氣和廢氣監(jiān)測(cè)分析方法》國(guó)家環(huán)保局編原子吸收法《固體廢棄物試驗(yàn)分析評(píng)價(jià)手冊(cè)》中國(guó)環(huán)境監(jiān)測(cè)總站等譯5.環(huán)境標(biāo)準(zhǔn):前蘇聯(lián)(1975)車(chē)間衛(wèi)生標(biāo)準(zhǔn)中國(guó)(待頒布)飲用水源水中有害物質(zhì)的很高容許濃度歐洲共同體(1980)飲用水中很高容許濃度10μg/L6.應(yīng)急處理處置方法:一、泄漏應(yīng)急處理隔離泄漏污染區(qū)，限制出入。切斷火源。建議應(yīng)急處理人員戴自給正壓式呼吸器，穿一般作業(yè)工作服。不要直接接觸泄漏物。小量泄漏：避免揚(yáng)塵，用潔凈的鏟子收集于干燥、潔凈、有蓋的容器中。轉(zhuǎn)移回收。大量泄漏：用塑料布、帆布覆蓋，減少飛散。然后轉(zhuǎn)移回收。二、防護(hù)措施呼吸系統(tǒng)防護(hù)：可能接觸其粉塵時(shí)，應(yīng)該佩戴自吸過(guò)濾式防塵口罩。必要時(shí)，佩戴空氣呼吸器、氧氣呼吸器或長(zhǎng)管面具。眼睛防護(hù)：戴化學(xué)安全防護(hù)眼鏡。身體防護(hù)：穿透氣型防毒服。手防護(hù)：戴防化學(xué)品手套。其它：工作現(xiàn)場(chǎng)禁止吸煙、進(jìn)食和飲水。工作畢，淋浴更衣。單獨(dú)存放被毒物污染的衣服，洗后備用。保持良好的衛(wèi)生習(xí)慣。三、急救措施皮膚接觸：脫去被污染的衣著，用肥皂水和清水徹底沖洗皮膚。眼睛接觸：提起眼瞼，用流動(dòng)清水或生理鹽水沖洗，就醫(yī)。吸入：迅速脫離現(xiàn)場(chǎng)至空氣新鮮處。它是一種有金屬光澤的類(lèi)金屬，在自然界中主要存在于硫化物礦物輝銻礦（SbS）中。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="西安5N銻粒廢料回收,銻" src="https://tyunfile.71360.com/UploadFile/scmhkj/637465971873430824/8939750.png"></div><p> 鹵化物銻能形成兩類(lèi)鹵化物——SbX3和SbX5。其中三鹵化物（SbF3、SbCl3、SbBr3和SbI3）的空間構(gòu)型都是三角錐形。三氟化銻可以由三氧化二銻與氫氟酸反應(yīng)制得：Sb2O3+6HF→2SbF3+3H2O這種氟化物是路易斯酸，能結(jié)合氟離子形成配離子SbF4?和SbF52?。熔化的三氟化銻是一種弱的導(dǎo)體。三氯化銻則由三硫化二銻溶于鹽酸制得：Sb2S3+6HCl→2SbCl3+3H2S五鹵化物（SbF5和SbCl5）氣態(tài)時(shí)的空間構(gòu)型為三角雙錐形。但是轉(zhuǎn)化為液態(tài)后，五氟化銻形成聚合物，而五氯化銻依舊是單體。五氟化銻是很強(qiáng)的路易斯酸，可用于配制有名的強(qiáng)很酸氟銻酸（HSbF6）。銻的鹵氧化物比砷和磷更為常見(jiàn)。三氧化二銻溶于濃酸再稀釋可形成銻?；衔铮鏢bOCl和(SbO)2SO4。[8]銻化物、氫化物與有機(jī)銻化合物這類(lèi)化合物通常被視作Sb的衍生物。Sb金屬性不強(qiáng)，能與金屬形成銻化物，例如銻化銦（InSb），銻化銀（Ag3Sb），銻鈀礦(Pd5Sb2)，方銻金礦(AuSb2)，紅銻鎳礦(NiSb)等。堿金屬和鋅的銻化物，例如Na3Sb和Zn3Sb2比以上物質(zhì)更為活潑。這些銻化物用酸處理可以生成不穩(wěn)定的氣體銻化氫（SbH3）。銻化物一般以共價(jià)鍵鏈接，是電子云的重疊，所以共價(jià)鍵很本質(zhì)的分類(lèi)方式就是它們的重疊方式。σ鍵，π鍵。易溶于王水，溶于濃硫酸。相對(duì)密度6.68。熔點(diǎn)630℃。沸點(diǎn)1635℃(1440℃)。湖南5N銻廢料回收</p><p style="text-indent:25px">在這種溫度和環(huán)境光線的作用下，亞穩(wěn)態(tài)的同素異形體會(huì)轉(zhuǎn)化成更穩(wěn)定的黑銻。西安5N銻粒廢料回收</p><p> 而且難以進(jìn)入一些利什曼原蟲(chóng)無(wú)鞭毛體所在的骨髓，也就無(wú)法治好影響內(nèi)臟的疾病。金屬銻制成的銻丸曾用作藥。但它被其他人從空氣中攝入后會(huì)導(dǎo)致中毒。在一些安全火柴的火柴頭中使用了三硫化二銻。銻-124和鈹一起用于中子源：銻-124釋放出伽馬射線，引發(fā)鈹?shù)墓庵峦懽?。這樣釋放出的中子平均能量為24keV。銻的硫化物已被證實(shí)可以穩(wěn)定汽車(chē)剎車(chē)片材料的摩擦系數(shù)。銻也用于制造道具和道具示蹤劑。這種元素也用于傳統(tǒng)的裝飾中，例如刷漆和藝術(shù)玻璃工藝。20世紀(jì)30年代前曾用它作牙釉質(zhì)的遮光劑，但是多次發(fā)生中毒后就不再使用了。銻安全編輯銻和它的許多化合物有毒，作用機(jī)理為壓抑酶的活性，這點(diǎn)與砷類(lèi)似；與同族的砷和鉍一樣，三價(jià)銻的毒性要比五價(jià)銻大。但是，銻的毒性比砷低得多，這可能是砷與銻之間在攝取、新陳代謝和排泄過(guò)程中的巨大差別所造成的：如三價(jià)銻和五價(jià)銻在消化道的吸收很多為20%；五價(jià)銻在細(xì)胞中不能被定量地還原為三價(jià)（事實(shí)上在細(xì)胞中三價(jià)銻反而會(huì)被氧化成五價(jià)銻）；由于體內(nèi)不能發(fā)生甲基化反應(yīng)，五價(jià)銻的主要排泄途徑是尿液。急性銻中毒的癥狀也與砷中毒相似，主要引起心臟毒性（表現(xiàn)為心肌炎），不過(guò)銻的心臟毒性還可能引起阿－斯綜合征。有報(bào)告稱(chēng)。西安5N銻粒廢料回收</p><p 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