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class="pic"><img src="https://tyunfile.71360.com/WaterMark/UploadFile/shlinchen/637278336133632812/8293857.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div><div id="ow20uko" class="smallimg"><div><p class="pic"><img src="https://tyunfile.71360.com/WaterMark/UploadFile/shlinchen/637278336133632812/8293857.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div></div><div id="qeks2w4" class="content"><p><span>需求數(shù)量：</span>0</p><p><span>價(jià)格要求：</span>面議</p><p><span>所在地：</span>上海市</p><p><span>包裝要求：</span><span style="color: #f30;"></span></p><p><span>產(chǎn)品關(guān)鍵詞：</span>99.9泛解酸內(nèi)酯要求</p><p><span>***更新：</span>2020-06-17 21:30:10</p><p><span id="click" >瀏覽次數(shù)：4次</span></p><a rel="nofollow" class="button">聯(lián)系我們</a></div></div><div id="2s4iygo" class="rightbox"><h3>公司基本資料信息</h3><p style="border:0;"><a rel="nofollow">上海臨辰醫(yī)藥科技有限公司</a></p><p><span>聯(lián)系人：</span>葉海岑</p><p><span>郵箱: </span>info@linchenpharm.com</p><p><span>電話: </span>13761181955</p><p><span>傳真: </span>021_</p><p><span>網(wǎng)址: </span></p><p><span>手機(jī): </span>021-31606595</p><p><span>地址: </span>辰花路5088弄221號(hào)</p><p>[當(dāng)前離線] <a rel="nofollow"> [加為商友] </a><a rel="nofollow"> [發(fā)送信件] </a></p></div></div><div id="ywkaosq" class="page-proshow02"><p class="title">詳細(xì)說(shuō)明</p><div id="ciyecgm" class="box"><p><p style="text-indent:25px">醇脫氫酶參與的化學(xué)酶法合成D-泛解酸內(nèi)酯與D- 泛解酸內(nèi)酯的工業(yè)合成類(lèi)似，從縮醛反應(yīng)出發(fā)再經(jīng)醇脫氫酶還原，99.9泛解酸內(nèi)酯要求， *經(jīng)過(guò)三步就合成了D- 泛解酸內(nèi)酯。這種醇脫氫酶參與的化學(xué)酶法合成過(guò)程由德國(guó)比勒費(fèi)爾德大學(xué)HEIDLINDEMANN M 等在2015 年設(shè)計(jì)以異丁醛和乙醛酸乙酯為起始原料，以L-組氨酸作為有機(jī)催化劑在酸性條件下發(fā)生醛醛縮合反應(yīng)，得到(R)-中間體1。醇脫氫酶以異丙醇為輔底物實(shí)現(xiàn)輔酶循環(huán)，99.9泛解酸內(nèi)酯要求，將中間體1 還原成中間體2，中間體2 無(wú)需分離直接自發(fā)環(huán)化成D-泛解酸內(nèi)酯，99.9泛解酸內(nèi)酯要求。反應(yīng)中D-泛解酸內(nèi)酯的總得率達(dá)55%，產(chǎn)物e.e.值達(dá)到95%。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="99.9泛解酸內(nèi)酯要求" src="https://tyunfile.71360.com/WaterMark/UploadFile/shlinchen/637278336133632812/8293857.png"></div><p style="text-indent:25px">氣態(tài)氫氰酸一般不產(chǎn)生聚合，但有水分凝聚時(shí)，會(huì)有聚合反應(yīng)出現(xiàn)，空氣(氧)并不促進(jìn)聚合反應(yīng)。液態(tài)氫氰酸或其水溶液，在堿性、高溫、長(zhǎng)時(shí)間放置、受光和放射線照射、放電以及電解條件下，都會(huì)引起聚合。聚合開(kāi)始后，產(chǎn)生的熱量又會(huì)引起聚合的連鎖反應(yīng)，從而加速聚合反應(yīng)的進(jìn)行，同時(shí)放出大量熱能，引起猛烈的，極限5.6%～40%(體積)。其蒸氣燃燒呈藍(lán)色火焰?？諝庵杏袣淝杷岽嬖跁r(shí)，用聯(lián)苯胺-乙酸銅試紙測(cè)定呈藍(lán)色反應(yīng)，用甲基橙-**(Ⅱ)試紙測(cè)定由橙色變粉紅色，用苦味酸一碳酸鈉試紙測(cè)定由黃色變?yōu)椴枭?/p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="99.9泛解酸內(nèi)酯要求" src="https://tyunfile.71360.com/WaterMark/UploadFile/shlinchen/637278336180390625/6214460.png"></div><p> D-泛酸在生物體內(nèi)的代謝途徑已經(jīng)確定，即經(jīng)α-酮異戊酸，利用酮泛解酸羥甲基轉(zhuǎn)移酶生成酮泛解酸，再利用酮泛解酸還原酶形成泛解酸，***與β-丙氨酸形成D-泛酸。目前，國(guó)內(nèi)對(duì)維生素B5 的年需求量達(dá)2 000 t 以上，而全球年需求量達(dá)10 000 t以上 </p> <p> 化學(xué)法合成D-泛解酸內(nèi)酯，從低廉原料出發(fā)經(jīng)多步反應(yīng)合成，工藝成熟，但總體存在化學(xué)條件 </p> <p> 嚴(yán)苛、酸堿用量大和能耗較高等問(wèn)題。生物技術(shù)的發(fā)展為生物酶法合成D-泛解酸內(nèi)酯提供了充分的可行性。目前工業(yè)化合成D-泛解酸內(nèi)酯采用的是化學(xué)法與水解酶拆分法相結(jié)合的技術(shù)路線。 </p> <p> <br /> </p></p><br /><p>文章來(lái)源地址: http://www.cdcfah.com/cp/294229.html</p></div></div></div></div></div><div id="cs4aem2" class="page-right twoColRt"><div id="iwm2usi" class="box01 margin10 clearfix"><h3><a href="http://www.cdcfah.com/cp/">猜你喜歡</a></h3><div id="i2iq44m" class="recomPic likePro"><a href="http://www.cdcfah.com/cp/814588.html"><div><img src="http://tyunfile.71360.com/UpLoadFile/2019/11/1/14/637082168864691056_lgpj_5374157.jpg" alt="福建ZF配件哪家強(qiáng) 信息推薦自業(yè)物資供應(yīng)" class="vcenter" 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