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href="http://www.cdcfah.com/">首頁?<a href="http://www.cdcfah.com/cp/">產(chǎn)品供應</a>?<a href="http://www.cdcfah.com/cp/second-_yyby/">醫(yī)藥健康</a>?<a href="http://www.cdcfah.com/cp/third-yyby_zyfl/">制藥輔料</a>?l泛解酸內(nèi)酯來電咨詢上海臨辰供應</p><div id="uoi3ahj" class="leftbox clearfix"><h1>l泛解酸內(nèi)酯來電咨詢上海臨辰供應</h1><div id="3ipjl84" class="proBig"><div id="vtaskrj" class="bigimg"><div><p class="pic"><img src="https://tyunfile.71360.com/WaterMark/UploadFile/shlinchen/637278336180390625/6214460.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div><div id="cgiphjq" class="smallimg"><div><p class="pic"><img src="https://tyunfile.71360.com/WaterMark/UploadFile/shlinchen/637278336180390625/6214460.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div></div><div id="3fcjlco" class="content"><p><span>需求數(shù)量：</span>0</p><p><span>價格要求：</span>面議</p><p><span>所在地：</span>上海市</p><p><span>包裝要求：</span><span style="color: #f30;"></span></p><p><span>產(chǎn)品關鍵詞：</span>l泛解酸內(nèi)酯來電咨詢</p><p><span>***更新：</span>2020-06-18 10:26:52</p><p><span id="click" >瀏覽次數(shù)：2次</span></p><a rel="nofollow" class="button">聯(lián)系我們</a></div></div><div id="7o3fqsu" class="rightbox"><h3>公司基本資料信息</h3><p style="border:0;"><a rel="nofollow">上海臨辰醫(yī)藥科技有限公司</a></p><p><span>聯(lián)系人：</span>葉海岑</p><p><span>郵箱: </span>info@linchenpharm.com</p><p><span>電話: </span>13761181955</p><p><span>傳真: </span>021_</p><p><span>網(wǎng)址: </span></p><p><span>手機: </span>021-31606595</p><p><span>地址: </span>辰花路5088弄221號</p><p>[當前離線] <a rel="nofollow"> [加為商友] </a><a rel="nofollow"> [發(fā)送信件] </a></p></div></div><div id="7s9yvht" class="page-proshow02"><p class="title">詳細說明</p><div id="xqdkcjg" class="box"><p><p> D-泛酸鈣的制備方法主要有兩種：1)先化學合成DL-泛酸鈣，通過拆分DL-泛酸鈣而制得D-泛酸鈣。2)通過化學法或生物法拆分關鍵中間體DL-泛解酸內(nèi)酯得到D-泛解酸內(nèi)酯，再由D-泛解酸內(nèi)酯與β--氨基丙酸反應合成D-泛酸鈣，其中生物法拆分的成本比化學法拆分的成本低15%。 </p> <p> 國外D-泛酸鈣生產(chǎn)公司主要有日本制藥精細化學品公司、德國BASF公司、荷蘭DSM公司等。BASF，l泛解酸內(nèi)酯來電咨詢、DSM均采用化學法生產(chǎn)，l泛解酸內(nèi)酯來電咨詢，而日本***制藥采用生物法酶拆分工藝制備中間體D-泛解酸內(nèi)酯，l泛解酸內(nèi)酯來電咨詢，這也是目前**技術的工藝。國內(nèi)原只有鑫富藥業(yè)一家有生物法酶拆分工藝，但現(xiàn)在山東新發(fā)也采用了這一工藝。 </p> <p> <br /> </p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="l泛解酸內(nèi)酯來電咨詢" src="https://tyunfile.71360.com/WaterMark/UploadFile/shlinchen/637278336180390625/6214460.png"></div><p style="text-indent:25px">早在1973 年，KING H L 等就研究發(fā)現(xiàn)一種來源于釀酒酵母的NADP（H）依賴型的酮泛解酸還原酶能夠?qū)⑼航馑徇€原為D-泛解酸內(nèi)酯，該酶在pH 7.0 條件下需要2.2 min 反應延滯期才會催化酮泛解酸內(nèi)酯形成D-泛解酸內(nèi)酯。1984 年，日本學者SHIMIZU S 等篩選了一系列能夠還原酮泛解酸內(nèi)酯形成泛解酸內(nèi)酯的微生物菌種，其中小紅酵母、不對稱擲孢酵母、**滑假絲酵母、粟酒裂殖酵母、清酒酵母、黑曲霉和萱草絲衣霉菌能夠催化酮泛解酸內(nèi)酯形成D-泛解酸內(nèi)酯。1987 年SHIMIZU S等利用氧化還原系統(tǒng)從消旋化的泛解酸內(nèi)酯出發(fā)，經(jīng)諾卡式菌選擇性氧化L-泛解酸內(nèi)酯生成酮泛解酸內(nèi)酯，后者經(jīng)**滑假絲酵母不對稱還原成D-泛解酸內(nèi)酯。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="l泛解酸內(nèi)酯來電咨詢" src="https://tyunfile.71360.com/WaterMark/UploadFile//637280289509208985/415071.png"></div><p style="text-indent:25px">水解酶催化選擇性拆分制備D-泛解酸內(nèi)酯DL-泛解酸內(nèi)酯可經(jīng)手性拆分得到所需要的D-泛解酸內(nèi)酯。化學法拆分所需的化學拆分劑或結(jié)晶操作一般較為昂貴，而利用水解酶催化的動力學拆分，具有節(jié)能環(huán)保、產(chǎn)品光學純度高等優(yōu)點，更適用于工業(yè)生產(chǎn)。水解酶選擇性水解泛解酸內(nèi)酯，根據(jù)選擇性可分為L-泛解酸內(nèi)酯水解酶和D-泛解酸內(nèi)酯水解酶。DL-泛解酸內(nèi)酯經(jīng)L-泛解酸內(nèi)酯水解酶水解，留下D-泛解酸內(nèi)酯，產(chǎn)生的L-泛解酸再經(jīng)化學內(nèi)酯、外消旋轉(zhuǎn)為DL-泛解酸內(nèi)酯。已知的L-泛解酸內(nèi)酯水解酶，大多來源于細菌，如多形無色桿菌、蘇云金芽孢桿菌、放射性土壤桿菌、根*農(nóng)桿菌。</p></p><br /><p>文章來源地址: http://www.cdcfah.com/cp/300660.html</p></div></div></div></div></div><div id="8j97izb" class="page-right twoColRt"><div id="scbyvce" class="box01 margin10 clearfix"><h3><a href="http://www.cdcfah.com/cp/">猜你喜歡</a></h3><div id="u7h37vs" class="recomPic likePro"><a href="http://www.cdcfah.com/cp/814588.html"><div><img src="http://tyunfile.71360.com/UpLoadFile/2019/11/1/14/637082168864691056_lgpj_5374157.jpg" 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