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href="http://www.cdcfah.com/cp/second-_yyby/">醫(yī)藥健康</a>?<a href="http://www.cdcfah.com/cp/third-yyby_zyfl/">制藥輔料</a>?l泛解酸內(nèi)酯有哪些品牌上海臨辰供應(yīng)</p><div id="bnsnsxh" class="leftbox clearfix"><h1>l泛解酸內(nèi)酯有哪些品牌上海臨辰供應(yīng)</h1><div id="3wrekfk" class="proBig"><div id="7ste88v" class="bigimg"><div><p class="pic"><img src="https://tyunfile.71360.com/WaterMark/UploadFile//637280289625869141/3735503.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div><div id="333jjpk" class="smallimg"><div><p class="pic"><img src="https://tyunfile.71360.com/WaterMark/UploadFile//637280289625869141/3735503.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div></div><div id="uwqvi8e" class="content"><p><span>需求數(shù)量：</span>0</p><p><span>價格要求：</span>面議</p><p><span>所在地：</span>上海市</p><p><span>包裝要求：</span><span style="color: #f30;"></span></p><p><span>產(chǎn)品關(guān)鍵詞：</span>l泛解酸內(nèi)酯有哪些品牌</p><p><span>***更新：</span>2020-06-21 22:28:19</p><p><span id="click" >瀏覽次數(shù)：0次</span></p><a rel="nofollow" class="button">聯(lián)系我們</a></div></div><div id="2y3tjzy" class="rightbox"><h3>公司基本資料信息</h3><p style="border:0;"><a rel="nofollow">上海臨辰醫(yī)藥科技有限公司</a></p><p><span>聯(lián)系人：</span>葉海岑</p><p><span>郵箱: </span>info@linchenpharm.com</p><p><span>電話: </span>13761181955</p><p><span>傳真: </span>021_</p><p><span>網(wǎng)址: </span></p><p><span>手機: </span>021-31606595</p><p><span>地址: </span>辰花路5088弄221號</p><p>[當(dāng)前離線] <a rel="nofollow"> [加為商友] </a><a rel="nofollow"> [發(fā)送信件] </a></p></div></div><div id="szz7uuf" class="page-proshow02"><p class="title">詳細說明</p><div id="dakuk8u" class="box"><p><p> D-泛解酸內(nèi)酯的傳統(tǒng)工業(yè)方法是化學(xué)拆分法和生物拆分法。 </p> <p> <br /> </p> <p> 這兩種方法生產(chǎn)過程復(fù)雜，拆分試劑制備回收繁瑣，l泛解酸內(nèi)酯有哪些品牌，生產(chǎn)成本高。 </p> <p> <br /> </p> <p> 探求其新的拆分方法，完善生產(chǎn)工藝，提高產(chǎn)品質(zhì)量，一直成為研究者和生產(chǎn)者追求的目的。 </p> <p> <br /> </p> <p> 實質(zhì)上在拆分工藝的三種傳統(tǒng)方法中（化學(xué)拆分、生物拆分、誘導(dǎo)拆分），l泛解酸內(nèi)酯有哪些品牌。 </p> <p> <br /> </p> <p> 生產(chǎn)D-泛酸鈣進行了幾十年的摸索，先后采用了誘導(dǎo)拆分DL-泛酸鈣法，l泛解酸內(nèi)酯有哪些品牌、化學(xué)拆分D-泛解酸內(nèi)酯法和生物拆分法。 </p> <p> <br /> </p> <p> 生產(chǎn)D-泛酸鈣，近年來拆分方法基本上統(tǒng)一到了生物拆分制備法。 </p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="l泛解酸內(nèi)酯有哪些品牌" src="https://tyunfile.71360.com/WaterMark/UploadFile//637280289625869141/3735503.png"></div><p style="text-indent:25px">早在1973 年，KING H L 等就研究發(fā)現(xiàn)一種來源于釀酒酵母的NADP（H）依賴型的酮泛解酸還原酶能夠?qū)⑼航馑徇€原為D-泛解酸內(nèi)酯，該酶在pH 7.0 條件下需要2.2 min 反應(yīng)延滯期才會催化酮泛解酸內(nèi)酯形成D-泛解酸內(nèi)酯。1984 年，日本學(xué)者SHIMIZU S 等篩選了一系列能夠還原酮泛解酸內(nèi)酯形成泛解酸內(nèi)酯的微生物菌種，其中小紅酵母、不對稱擲孢酵母、**滑假絲酵母、粟酒裂殖酵母、清酒酵母、黑曲霉和萱草絲衣霉菌能夠催化酮泛解酸內(nèi)酯形成D-泛解酸內(nèi)酯。1987 年SHIMIZU S等利用氧化還原系統(tǒng)從消旋化的泛解酸內(nèi)酯出發(fā)，經(jīng)諾卡式菌選擇性氧化L-泛解酸內(nèi)酯生成酮泛解酸內(nèi)酯，后者經(jīng)**滑假絲酵母不對稱還原成D-泛解酸內(nèi)酯。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="l泛解酸內(nèi)酯有哪些品牌" src="https://tyunfile.71360.com/WaterMark/UploadFile/shlinchen/637278336180390625/6214460.png"></div><p style="text-indent:25px">醇脫氫酶參與的化學(xué)酶法合成D-泛解酸內(nèi)酯與D- 泛解酸內(nèi)酯的工業(yè)合成類似，從縮醛反應(yīng)出發(fā)再經(jīng)醇脫氫酶還原， *經(jīng)過三步就合成了D- 泛解酸內(nèi)酯。這種醇脫氫酶參與的化學(xué)酶法合成過程由德國比勒費爾德大學(xué)HEIDLINDEMANN M 等在2015 年設(shè)計以異丁醛和乙醛酸乙酯為起始原料，以L-組氨酸作為有機催化劑在酸性條件下發(fā)生醛醛縮合反應(yīng)，得到(R)-中間體1。醇脫氫酶以異丙醇為輔底物實現(xiàn)輔酶循環(huán)，將中間體1 還原成中間體2，中間體2 無需分離直接自發(fā)環(huán)化成D-泛解酸內(nèi)酯。反應(yīng)中D-泛解酸內(nèi)酯的總得率達55%，產(chǎn)物e.e.值達到95%。</p></p><br /><p>文章來源地址: http://www.cdcfah.com/cp/343165.html</p></div></div></div></div></div><div id="yp3eufp" class="page-right twoColRt"><div id="3tkpuuo" class="box01 margin10 clearfix"><h3><a href="http://www.cdcfah.com/cp/">猜你喜歡</a></h3><div 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