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src="https://tyunfile.71360.com/WaterMark/UploadFile/shlinchen/637278336133632812/8293857.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div><div id="rpqhdza" class="smallimg"><div><p class="pic"><img src="https://tyunfile.71360.com/WaterMark/UploadFile/shlinchen/637278336133632812/8293857.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div></div><div id="pnefbx7" class="content"><p><span>需求數(shù)量：</span>0</p><p><span>價格要求：</span>面議</p><p><span>所在地：</span>上海市</p><p><span>包裝要求：</span><span style="color: #f30;"></span></p><p><span>產(chǎn)品關(guān)鍵詞：</span>高純泛解酸內(nèi)酯型號</p><p><span>***更新：</span>2020-06-22 19:28:23</p><p><span id="click" >瀏覽次數(shù)：0次</span></p><a rel="nofollow" class="button">聯(lián)系我們</a></div></div><div id="sq8kbhd" class="rightbox"><h3>公司基本資料信息</h3><p style="border:0;"><a rel="nofollow">上海臨辰醫(yī)藥科技有限公司</a></p><p><span>聯(lián)系人：</span>葉海岑</p><p><span>郵箱: </span>info@linchenpharm.com</p><p><span>電話: </span>13761181955</p><p><span>傳真: </span>021_</p><p><span>網(wǎng)址: </span></p><p><span>手機(jī): </span>021-31606595</p><p><span>地址: </span>辰花路5088弄221號</p><p>[當(dāng)前離線] <a rel="nofollow"> [加為商友] </a><a rel="nofollow"> [發(fā)送信件] </a></p></div></div><div id="yg3a2zs" class="page-proshow02"><p class="title">詳細(xì)說明</p><div id="aiefgms" class="box"><p><p style="text-indent:25px">醇脫氫酶參與的化學(xué)酶法合成D-泛解酸內(nèi)酯與D- 泛解酸內(nèi)酯的工業(yè)合成類似，從縮醛反應(yīng)出發(fā)再經(jīng)醇脫氫酶還原， *經(jīng)過三步就合成了D- 泛解酸內(nèi)酯。這種醇脫氫酶參與的化學(xué)酶法合成過程由德國比勒費爾德大學(xué)HEIDLINDEMANN M 等在2015 年設(shè)計以異丁醛和乙醛酸乙酯為起始原料，以L-組氨酸作為有機(jī)催化劑在酸性條件下發(fā)生醛醛縮合反應(yīng)，得到(R)-中間體1。醇脫氫酶以異丙醇為輔底物實現(xiàn)輔酶循環(huán)，高純泛解酸內(nèi)酯型號，將中間體1 還原成中間體2，中間體2 無需分離直接自發(fā)環(huán)化成D-泛解酸內(nèi)酯。反應(yīng)中D-泛解酸內(nèi)酯的總得率達(dá)55%，高純泛解酸內(nèi)酯型號，高純泛解酸內(nèi)酯型號，產(chǎn)物e.e.值達(dá)到95%。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="高純泛解酸內(nèi)酯型號" src="https://tyunfile.71360.com/WaterMark/UploadFile/shlinchen/637278336133632812/8293857.png"></div><p> D-泛酸鈣的制備方法主要有兩種：1)先化學(xué)合成DL-泛酸鈣，通過拆分DL-泛酸鈣而制得D-泛酸鈣。2)通過化學(xué)法或生物法拆分關(guān)鍵中間體DL-泛解酸內(nèi)酯得到D-泛解酸內(nèi)酯，再由D-泛解酸內(nèi)酯與β--氨基丙酸反應(yīng)合成D-泛酸鈣，其中生物法拆分的成本比化學(xué)法拆分的成本低15%。 </p> <p> 國外D-泛酸鈣生產(chǎn)公司主要有日本制藥精細(xì)化學(xué)品公司、德國BASF公司、荷蘭DSM公司等。BASF、DSM均采用化學(xué)法生產(chǎn)，而日本***制藥采用生物法酶拆分工藝制備中間體D-泛解酸內(nèi)酯，這也是目前**技術(shù)的工藝。國內(nèi)原只有鑫富藥業(yè)一家有生物法酶拆分工藝，但現(xiàn)在山東新發(fā)也采用了這一工藝。 </p> <p> <br /> </p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="高純泛解酸內(nèi)酯型號" src="https://tyunfile.71360.com/WaterMark/UploadFile/shlinchen/637278336299169921/7145872.png"></div><p> 該酶已經(jīng)成功的應(yīng)用于工業(yè)化,取得了很好的綜合效益.為了提高D-泛解酸內(nèi)酯水解酶的酶活力及在低pH條件下的穩(wěn)定性,我們在基因水平上對酶進(jìn)行了研究. 利用RT-PCR方法,擴(kuò)增得到了編碼源于串珠鐮孢霉菌(Fusarium moniliforme)CGMCC </p> <p> 0536的D-泛解酸內(nèi)酯水解酶cDNA,對其結(jié)構(gòu)進(jìn)行分析,根據(jù)分析結(jié)果設(shè)計了一對特異引物,成功擴(kuò)增到了編碼D-泛解酸內(nèi)酯水解酶cDNA的結(jié)構(gòu)基因,結(jié)構(gòu)基因同pMD18-T載體連接后,進(jìn)行測序.D-泛解酸內(nèi)酯水解酶cDNA結(jié)構(gòu)基因序列已在Genebank數(shù)據(jù)庫申請登記,登記號為AY728018. </p></p><br /><p>文章來源地址: http://www.cdcfah.com/cp/354044.html</p></div></div></div></div></div><div id="2cyj78w" class="page-right twoColRt"><div id="3ghstu3" class="box01 margin10 clearfix"><h3><a href="http://www.cdcfah.com/cp/">猜你喜歡</a></h3><div id="ow7lzp8" class="recomPic likePro"><a href="http://www.cdcfah.com/cp/814588.html"><div><img src="http://tyunfile.71360.com/UpLoadFile/2019/11/1/14/637082168864691056_lgpj_5374157.jpg" alt="福建ZF配件哪家強(qiáng) 信息推薦自業(yè)物資供應(yīng)" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></div><p>福建ZF配件哪家強(qiáng) 信息推薦自業(yè)物資供應(yīng)</p></a></div><div id="n8uvmst" class="recomPic likePro"><a href="http://www.cdcfah.com/cp/846569.html"><div><img 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