DL泛解酸內(nèi)酯源頭好貨上海臨辰供應(yīng)-b2b網(wǎng)站_b2b電子商務(wù)平臺(tái)【買(mǎi)產(chǎn)品】-上?？谄蚴称酚邢薰?/title><meta name="description" content="采用異丁醛、甲醛和**為原料經(jīng)過(guò)化學(xué)合成獲得DL-泛解酸內(nèi)酯；采用酶拆分工藝制備中間體D-泛解酸內(nèi)酯是目前**技術(shù)的工藝。D-泛解酸內(nèi)酯是合成D-泛酸的重要中間體。DL-泛解酸內(nèi)酯再在串珠鐮孢霉菌的作用下生成D-泛解酸，經(jīng)內(nèi)酯化獲得D-泛"><meta name="keywords" content="DL泛解酸內(nèi)酯源頭好貨"><link rel="canonical" href="http://www.cdcfah.com/"/><meta name="applicable-device" content="pc"><link rel="shortcut icon" href="/static/new_net_01/images/favicon.ico"><link rel="stylesheet" href="/static/new_net_01/css/slick.css" /><link rel="stylesheet" href="/static/new_net_01/css/addnew.css"><link rel="stylesheet" href="/static/new_net_01/css/sidenav.css"><link rel="stylesheet" href="/static/new_net_01/css/style.css" /><link rel="stylesheet" href="/static/new_net_01/css/tab.css"><link rel="stylesheet" href="/static/new_net_01/css/404.css"> <meta name="baidu-site-verification" content="OBVzrC9aaQ" /> <meta http-equiv="Cache-Control" 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class="pic"><img src="https://tyunfile.71360.com/WaterMark/UploadFile//637280289509208985/415071.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div><div id="lev7ono" class="smallimg"><div><p class="pic"><img src="https://tyunfile.71360.com/WaterMark/UploadFile//637280289509208985/415071.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div></div><div id="3wsy2ar" class="content"><p><span>需求數(shù)量：</span>0</p><p><span>價(jià)格要求：</span>面議</p><p><span>所在地：</span>上海市</p><p><span>包裝要求：</span><span style="color: #f30;"></span></p><p><span>產(chǎn)品關(guān)鍵詞：</span>DL泛解酸內(nèi)酯源頭好貨</p><p><span>***更新：</span>2020-06-27 12:27:05</p><p><span id="click" >瀏覽次數(shù)：0次</span></p><a rel="nofollow" class="button">聯(lián)系我們</a></div></div><div id="7jarx3y" class="rightbox"><h3>公司基本資料信息</h3><p style="border:0;"><a rel="nofollow">上海臨辰醫(yī)藥科技有限公司</a></p><p><span>聯(lián)系人：</span>葉海岑</p><p><span>郵箱: </span>info@linchenpharm.com</p><p><span>電話: </span>13761181955</p><p><span>傳真: </span>021_</p><p><span>網(wǎng)址: </span></p><p><span>手機(jī): </span>021-31606595</p><p><span>地址: </span>辰花路5088弄221號(hào)</p><p>[當(dāng)前離線] <a rel="nofollow"> [加為商友] </a><a rel="nofollow"> [發(fā)送信件] </a></p></div></div><div id="8w7zquq" class="page-proshow02"><p class="title">詳細(xì)說(shuō)明</p><div id="vdevcs7" class="box"><p><p> 采用異丁醛、甲醛和**為原料經(jīng)過(guò)化學(xué)合成獲得DL-泛解酸內(nèi)酯； </p> <p> 采用酶拆分工藝制備中間體D-泛解酸內(nèi)酯是目前**技術(shù)的工藝。 </p> <p> D-泛解酸內(nèi)酯是合成D-泛酸的重要中間體。 </p> <p> <br /> </p> <p> DL-泛解酸內(nèi)酯再在串珠鐮孢霉菌的作用下生成D-泛解酸，經(jīng)內(nèi)酯化獲得D-泛解酸內(nèi)酯，DL泛解酸內(nèi)酯源頭好貨。 </p> <p> <br /> </p> <p> 在培養(yǎng)基中培養(yǎng)尖孢鐮孢菌，在培養(yǎng)后的尖孢鐮孢菌與底物混合，DL泛解酸內(nèi)酯源頭好貨，水解得到D-泛解酸，DL泛解酸內(nèi)酯源頭好貨。 </p> <p> <br /> </p> <p> 內(nèi)酯化獲得D-泛解酸內(nèi)酯，但是本方法采用發(fā)酵制備D-泛解酸內(nèi)酯的過(guò)程能耗較高，且產(chǎn)率低，工業(yè)成本較高。 </p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="DL泛解酸內(nèi)酯源頭好貨" src="https://tyunfile.71360.com/WaterMark/UploadFile//637280289509208985/415071.png"></div><p style="text-indent:25px">其中Kataoka M 等發(fā)現(xiàn)來(lái)源于根*農(nóng)桿菌的L-泛解酸內(nèi)酯水解酶有較高的活力和選擇性。Kesseler M 等對(duì)根*農(nóng)桿菌lu678 的L-泛解酸內(nèi)酯水解酶構(gòu)建大腸工程菌并過(guò)量表達(dá)該蛋白，酶活提高了200 倍，達(dá)到600 U/g。該過(guò)程要求L-泛解酸內(nèi)酯必須完全水解，才能獲得高光學(xué)純度的D-泛解酸內(nèi)酯，限制了其工業(yè)應(yīng)用。D-泛解酸內(nèi)酯水解酶選擇性水解拆分DL-泛解酸內(nèi)酯生成D-泛解酸，再經(jīng)內(nèi)酯化生成D-泛解酸內(nèi)酯，留下的L-泛解酸內(nèi)酯經(jīng)化學(xué)消旋化為DL-泛解酸內(nèi)酯重新循環(huán)拆分。D-泛解酸內(nèi)酯水解酶來(lái)源豐富，其中**常用的是鐮飽霉菌，有尖孢鐮刀菌、腐皮鐮刀菌和串珠鐮刀菌。2007 年，SAKAMOTO K等利用固定化的尖孢鐮刀菌來(lái)水解拆分DL-泛解酸內(nèi)酯，固定化細(xì)胞的半衰期可以達(dá)到6 000h，經(jīng)過(guò)180次重復(fù)利用后仍然保持原活力的71%，相對(duì)于游離的整細(xì)胞催化其半衰期提高了35 倍。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="DL泛解酸內(nèi)酯源頭好貨" src="https://tyunfile.71360.com/WaterMark/UploadFile/shlinchen/637278339844755859/788254.png"></div><p style="text-indent:25px">羥基腈裂合酶催化不對(duì)稱(chēng)合成D-泛解酸內(nèi)酯前體(R)-氰醇(R)-氰醇是D-泛解酸內(nèi)酯的前體物質(zhì)，可經(jīng)過(guò)水解生產(chǎn)D-泛解酸內(nèi)酯。利用(R)-羥基腈裂合酶催化HCN 與羥基特戊醛的羰基碳不對(duì)稱(chēng)加成進(jìn)而合成(R)-氰醇。大多數(shù)參與醇腈化反應(yīng)的酶主要存在于高等植物中，例如巴旦杏、蘋(píng)果、薔薇、橡膠樹(shù)、亞麻類(lèi)等，在植物體內(nèi)羥基腈裂解酶催化形成氫腈酸從而抵御外來(lái)物種的入侵。2007 年荷蘭DSM 公司從巴旦杏中提取分離的(R)-羥基腈裂合酶能選擇性合成(R)-氰醇，并構(gòu)建了粟酒裂殖酵母工程菌。2014 年，DSM 公司將來(lái)自薔薇科的(R)-羥基腈裂合酶基因構(gòu)建于pJET 重組質(zhì)粒，并導(dǎo)入巴斯德酵母中表達(dá)，確定了該重組酶**適條件范圍為15~20 ℃以及pH 2.5~3.0。在15 ℃和pH 2.5 下醇腈化反應(yīng)2 d，反應(yīng)收率達(dá)到93%，轉(zhuǎn)化率達(dá)**，產(chǎn)物光學(xué)純度達(dá)92%。</p></p><br /><p>文章來(lái)源地址: http://www.cdcfah.com/cp/411046.html</p></div></div></div></div></div><div id="uhikqx2" class="page-right twoColRt"><div id="emdpg2f" class="box01 margin10 clearfix"><h3><a href="http://www.cdcfah.com/cp/">猜你喜歡</a></h3><div id="3o3rxd3" class="recomPic likePro"><a href="http://www.cdcfah.com/cp/814588.html"><div><img 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