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#f30;"></span></p><p><span>產(chǎn)品關(guān)鍵詞：</span>鎮(zhèn)江陽極封孔劑</p><p><span>***更新：</span>2020-06-03 05:19:42</p><p><span id="click" >瀏覽次數(shù)：0次</span></p><a rel="nofollow" class="button">聯(lián)系我們</a></div></div><div id="xlljzfd" class="rightbox"><h3>公司基本資料信息</h3><p style="border:0;"><a rel="nofollow">仙桃市百事德化工有限責(zé)任公司</a></p><p><span>聯(lián)系人：</span>謝進(jìn)濤</p><p><span>郵箱: </span>267304616@qq.com</p><p><span>電話: </span>15852535713</p><p><span>傳真: </span>0510_86380198</p><p><span>網(wǎng)址: </span></p><p><span>手機(jī): </span>0510-86380198</p><p><span>地址: </span>沙嘴街道光湖路8號</p><p>[當(dāng)前離線] <a rel="nofollow"> [加為商友] </a><a rel="nofollow"> [發(fā)送信件] </a></p></div></div><div id="bhnvtzd" class="page-proshow02"><p class="title">詳細(xì)說明</p><div id="xlj77fl" class="box"><p><p> 由此封閉工藝產(chǎn)生的廢水中的鎳含量〇.，其它添加劑的含量。[0005]由于長時(shí)間接觸鎳，輕者會(huì)引起皮炎，重者可能有致的危險(xiǎn)，因此我國加大了對鎳污染的控制力度，從2008年以來，對于國土開發(fā)密度較高、環(huán)境承載能力減弱地區(qū)，如珠三角地和長三角的部分地區(qū)嚴(yán)格執(zhí)行中華人民國家標(biāo)準(zhǔn)《電鍍污染物排放標(biāo)準(zhǔn)》(GB21900-2008)中的表3規(guī)定水污染物特別排放限值，其中總鎳的含量不超過。為了滿足環(huán)保標(biāo)準(zhǔn)的要求，大多數(shù)企業(yè)將這類含鎳廢水與其他廢水分開，單獨(dú)處理。[0006]目前，常用的處理含鎳廢水方法有化學(xué)沉淀法（即用堿調(diào)節(jié)含鎳廢水pH值，并加金屬補(bǔ)集劑等中和、混凝、絮凝、沉淀）、離子交換法、吸附法、電滲析法、蒸發(fā)濃縮法和反滲法等。其中離子交換法及吸附法對絡(luò)合態(tài)的大分子無法有效破除；電滲析法及反滲透對膜的要求很高，鎮(zhèn)江陽極封孔劑，容易造成膜的破壞;蒸發(fā)濃縮法對設(shè)備要求高，鎮(zhèn)江陽極封孔劑，需要用到熱源，處理能耗高，鎮(zhèn)江陽極封孔劑。[0007]中國**CN。[0008]中國**CN2采用陰離子交換樹脂吸附鎳離子的陽極著色廢水處理方法。[0009]上述兩種方法處理后的廢水均無法持續(xù)穩(wěn)定地達(dá)到國家一級排放標(biāo)準(zhǔn)，會(huì)導(dǎo)致環(huán)境污染。造成鎳離子超標(biāo)的原因在于封孔溶液中含有能與鎳離子形成穩(wěn)定絡(luò)合物的絡(luò)合劑。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="鎮(zhèn)江陽極封孔劑" src="https://tyunfile.71360.com/UploadFile/xtsbsd1/637262913937138672/5901259.png"></div><p> 日常生活中接觸到的各種鋁合金外殼，表面含鎳，對人體造成的持續(xù)傷害，已日益引起社會(huì)的高度重視。采用氟鈦酸封孔，其封孔成分為氫氧化鈦，徹底，正好適應(yīng)鋁合金日益深入人類日常生活各方面的大趨勢。但如何用好氟鈦酸，技術(shù)難度非常大。按（3）式，pH升高，氟鈦酸分解出氫氧化鈦，正好是所需要的封孔成分。按（2）式，氟鈦酸水解，電離出F-；按（4）式，F(xiàn)-與氧化膜反應(yīng)，釋放出OH-，使槽液pH升高。F-是促進(jìn)封孔物質(zhì)氫氧化鈦和氟鋁絡(luò)合物Al2(OH)3F3形成的關(guān)鍵離子。如上所述，氟鈦酸有鈦有氟，完全可作為封孔劑的主要成分，且封孔速度快，封孔溫度低。但研發(fā)中遇到以下幾個(gè)致命難題：（1）從分子式看，氟鈦酸與氟化鎳相比，氟太高，易結(jié)粉霜;（2）氟鈦酸pH工作點(diǎn)太低，當(dāng)pH值大于，槽液分解，形成氫氧化鈦沉淀，封孔優(yōu)化區(qū)間只能在3-4之間；（3）氟高，pH值低，鋁合金表面氧化膜易被腐蝕；（4）氟高，pH值低，溶鋁量太大，槽液易渾濁，鋁合金易上粉。只有解決高氟、低pH值下氧化膜被腐蝕、鋁合金上粉、槽液渾濁的難題，才能有效使用氟鈦酸，實(shí)現(xiàn)無鎳封孔。為此，選用緩蝕劑和螯合劑，與氟鈦酸配伍，解決高氟、低pH值下鋁合金上粉和槽液渾濁難題。緩蝕劑。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="鎮(zhèn)江陽極封孔劑" src="https://tyunfile.71360.com/UploadFile/xtsbsd1/637262913996914063/9599976.png"></div><p> 粒徑?jīng)]有發(fā)生明顯改變，維持在114±9nm。圖4可以看出se-msns復(fù)合材料含有se，并可以成功制備出不同含se量的se-msns樣品。其晶型為六方晶型：(100)、(101)、(110)、(012)、(111)。圖5為se-msns對金黃色葡萄球菌的實(shí)驗(yàn)，從圖5a可以看出分散性不好的純se，即團(tuán)聚的se在24h前，并沒有表現(xiàn)出明顯的抑菌效果，24h才開始有明顯抑菌效果。而se-msns相較于較團(tuán)聚的se，對金黃色葡萄球菌有明顯的抑菌作用，其載se量分別為30wt.％和40wt.％時(shí)，在12h率即可達(dá)到％以上，作為對照的擴(kuò)孔的msns完全不具有明顯的性能。考慮到樣品能否可以進(jìn)行循環(huán)利用，對樣品40wt.％se-msns和純se進(jìn)行二次和三次離心回收，并重復(fù)實(shí)驗(yàn)，結(jié)果分別見圖5b和5c。圖5b表明，純se在進(jìn)行回收后沒有明顯的抑菌效果，而40wt.％se-msns比使用表現(xiàn)出更好的抑菌作用。圖5c表明第二次回收后，40wt.％se-msns具有比次回收更明顯的抑菌效果，在12h時(shí)的抑菌率達(dá)到％。本發(fā)明與中國**cna相比：(1)本發(fā)明載體msns進(jìn)行擴(kuò)孔，中國**cna中載體msns并未進(jìn)行擴(kuò)孔，本發(fā)明和中國**cna中msns比較見表s-1；(2)本發(fā)明采用超聲輔助-熔融滲透方法制備se/msns，中國**cna采用的是溶膠凝膠原位方法；。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="鎮(zhèn)江陽極封孔劑" src="https://tyunfile.71360.com/UploadFile/xtsbsd1/637262913898906250/6931910.png"></div></p><br /><p>文章來源地址: 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