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href="http://www.cdcfah.com/cp/">產(chǎn)品供應(yīng)</a>?<a href="http://www.cdcfah.com/cp/second-_jxhxp/">精細(xì)化學(xué)品</a>?<a href="http://www.cdcfah.com/cp/third-jxhxp_qitazhuji/">其他助劑</a>?南通無(wú)鎳封孔劑廠仙桃市百事德化工供應(yīng)</p><div id="ztvnslk" class="leftbox clearfix"><h1>南通無(wú)鎳封孔劑廠仙桃市百事德化工供應(yīng)</h1><div id="joqs48m" class="proBig"><div id="jd7vszb" class="bigimg"><div><p class="pic"><img src="https://tyunfile.71360.com/UploadFile/xtsbsd1/637262913898906250/6931910.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div><div id="rgd3dxt" class="smallimg"><div><p class="pic"><img src="https://tyunfile.71360.com/UploadFile/xtsbsd1/637262913898906250/6931910.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div></div><div id="xhjlkby" class="content"><p><span>需求數(shù)量：</span>0</p><p><span>價(jià)格要求：</span>面議</p><p><span>所在地：</span>湖北省</p><p><span>包裝要求：</span><span style="color: #f30;"></span></p><p><span>產(chǎn)品關(guān)鍵詞：</span>南通無(wú)鎳封孔劑廠</p><p><span>***更新：</span>2020-06-06 07:17:46</p><p><span id="click" >瀏覽次數(shù)：0次</span></p><a rel="nofollow" class="button">聯(lián)系我們</a></div></div><div id="qphzofr" class="rightbox"><h3>公司基本資料信息</h3><p style="border:0;"><a rel="nofollow">仙桃市百事德化工有限責(zé)任公司</a></p><p><span>聯(lián)系人：</span>謝進(jìn)濤</p><p><span>郵箱: </span>267304616@qq.com</p><p><span>電話: </span>15852535713</p><p><span>傳真: </span>0510_86380198</p><p><span>網(wǎng)址: </span></p><p><span>手機(jī): </span>0510-86380198</p><p><span>地址: </span>沙嘴街道光湖路8號(hào)</p><p>[當(dāng)前離線] <a rel="nofollow"> [加為商友] </a><a rel="nofollow"> [發(fā)送信件] </a></p></div></div><div id="3pz28sh" class="page-proshow02"><p class="title">詳細(xì)說(shuō)明</p><div id="3utkryk" class="box"><p><p> 粒徑?jīng)]有發(fā)生明顯改變，維持在114±9nm。圖4可以看出se-msns復(fù)合材料含有se，南通無(wú)鎳封孔劑廠，并可以成功制備出不同含se量的se-msns樣品。其晶型為六方晶型：(100)、(101)、(110)、(012)、(111)。圖5為se-msns對(duì)金黃色葡萄球菌的實(shí)驗(yàn)，從圖5a可以看出分散性不好的純se，即團(tuán)聚的se在24h前，并沒有表現(xiàn)出明顯的抑菌效果，24h才開始有明顯抑菌效果。而se-msns相較于較團(tuán)聚的se，對(duì)金黃色葡萄球菌有明顯的抑菌作用，其載se量分別為30wt.％和40wt.％時(shí)，在12h率即可達(dá)到％以上，作為對(duì)照的擴(kuò)孔的msns完全不具有明顯的性能?？紤]到樣品能否可以進(jìn)行循環(huán)利用，對(duì)樣品40wt.％se-msns和純se進(jìn)行二次和三次離心回收，并重復(fù)實(shí)驗(yàn)，結(jié)果分別見圖5b和5c。圖5b表明，南通無(wú)鎳封孔劑廠，純se在進(jìn)行回收后沒有明顯的抑菌效果，而40wt.％se-msns比使用表現(xiàn)出更好的抑菌作用。圖5c表明第二次回收后，南通無(wú)鎳封孔劑廠，40wt.％se-msns具有比次回收更明顯的抑菌效果，在12h時(shí)的抑菌率達(dá)到％。本發(fā)明與中國(guó)**cna相比：(1)本發(fā)明載體msns進(jìn)行擴(kuò)孔，中國(guó)**cna中載體msns并未進(jìn)行擴(kuò)孔，本發(fā)明和中國(guó)**cna中msns比較見表s-1；(2)本發(fā)明采用超聲輔助-熔融滲透方法制備se/msns，中國(guó)**cna采用的是溶膠凝膠原位方法；。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="南通無(wú)鎳封孔劑廠" src="https://tyunfile.71360.com/UploadFile/xtsbsd1/637262913898906250/6931910.png"></div><p> 日常生活中接觸到的各種鋁合金外殼，表面含鎳，對(duì)人體造成的持續(xù)傷害，已日益引起社會(huì)的高度重視。采用氟鈦酸封孔，其封孔成分為氫氧化鈦，徹底，正好適應(yīng)鋁合金日益深入人類日常生活各方面的大趨勢(shì)。但如何用好氟鈦酸，技術(shù)難度非常大。按（3）式，pH升高，氟鈦酸分解出氫氧化鈦，正好是所需要的封孔成分。按（2）式，氟鈦酸水解，電離出F-；按（4）式，F(xiàn)-與氧化膜反應(yīng)，釋放出OH-，使槽液pH升高。F-是促進(jìn)封孔物質(zhì)氫氧化鈦和氟鋁絡(luò)合物Al2(OH)3F3形成的關(guān)鍵離子。如上所述，氟鈦酸有鈦有氟，完全可作為封孔劑的主要成分，且封孔速度快，封孔溫度低。但研發(fā)中遇到以下幾個(gè)致命難題：（1）從分子式看，氟鈦酸與氟化鎳相比，氟太高，易結(jié)粉霜;（2）氟鈦酸pH工作點(diǎn)太低，當(dāng)pH值大于，槽液分解，形成氫氧化鈦沉淀，封孔優(yōu)化區(qū)間只能在3-4之間；（3）氟高，pH值低，鋁合金表面氧化膜易被腐蝕；（4）氟高，pH值低，溶鋁量太大，槽液易渾濁，鋁合金易上粉。只有解決高氟、低pH值下氧化膜被腐蝕、鋁合金上粉、槽液渾濁的難題，才能有效使用氟鈦酸，實(shí)現(xiàn)無(wú)鎳封孔。為此，選用緩蝕劑和螯合劑，與氟鈦酸配伍，解決高氟、低pH值下鋁合金上粉和槽液渾濁難題。緩蝕劑。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="南通無(wú)鎳封孔劑廠" src="https://tyunfile.71360.com/UploadFile/xtsbsd1/637262913937138672/5901259.png"></div><p> 在以氟鈦酸為封孔主要成分的無(wú)鎳封孔液新配方條件下，工藝參數(shù)有很大的變化：封孔溫度15-35℃封孔速度1-3um/min槽液PHF-濃度氟鈦酸自帶，不專門限制（7）H2TiF6(50%)濃度比較式(6)與(7)，氟鈦酸的封孔能力比氟化鎳強(qiáng)，封孔溫度下限由25℃拓寬至15℃，封孔速度1um/min提高至3um/min，槽液，但范圍拓寬。由于含大量螯合劑，新配方對(duì)水質(zhì)要求不高，開槽用自來(lái)水即可，所含Ca2+、Mg2+可被螯合劑完全屏蔽。氟化鎳封孔的F-濃度為，分子結(jié)構(gòu)中F-不夠，需要額外補(bǔ)氟；氟鈦酸分子結(jié)構(gòu)中，氟含量過(guò)高，為此，配方中專門設(shè)置緩蝕劑，降低氟的腐蝕能力，故F-按式（2），自動(dòng)水解平衡，無(wú)需檢測(cè)和控制。氟化鎳封孔的Ni2+濃度為，氟鈦酸槽液中鈦不是以Ti4+存在，而是以Ti(OH)3F32-+Ti(OH)2F42-+Ti(OH)F52-存在，故選用H2TiF6(50%)濃度。式（1）-（5）顯示封孔動(dòng)力學(xué)的全過(guò)程。式（1）表明氟鈦酸在槽液中電離成2H++TiF62-；式（2）表明氟鈦酸根在槽液中水解成Ti(OH)3F32-+Ti(OH)2F42-+Ti(OH)F52-，并釋放6H++6F-；式（4）表明F-在氧化膜微孔反應(yīng)，釋放出OH-，提高微孔中的pH值；式（3）表面在氧化膜微孔中，pH值的升高，Ti(OH)3F32-進(jìn)一步水解，生成封孔物資Ti(OH)4，完成封孔。由此可見。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="南通無(wú)鎳封孔劑廠" src="https://tyunfile.71360.com/UploadFile/xtsbsd1/637262913996914063/9599976.png"></div></p><br /><p>文章來(lái)源地址: 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