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src="https://tyunfile.71360.com/UploadFile/xtsbsd1/637262913937138672/5901259.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div><div id="dr8gipr" class="smallimg"><div><p class="pic"><img src="https://tyunfile.71360.com/UploadFile/xtsbsd1/637262913937138672/5901259.png" class="vcenter" onerror="javascript:this.src='/static/new_net_01/images/nopic.jpg';"></p></div></div></div><div id="8umofh2" class="content"><p><span>需求數(shù)量：</span>0</p><p><span>價格要求：</span>面議</p><p><span>所在地：</span>湖北省</p><p><span>包裝要求：</span><span style="color: #f30;"></span></p><p><span>產(chǎn)品關鍵詞：</span>南通無鎳封孔劑研究</p><p><span>***更新：</span>2020-06-29 15:30:34</p><p><span id="click" >瀏覽次數(shù)：0次</span></p><a rel="nofollow" class="button">聯(lián)系我們</a></div></div><div id="ig3bt7l" class="rightbox"><h3>公司基本資料信息</h3><p style="border:0;"><a rel="nofollow">仙桃市百事德化工有限責任公司</a></p><p><span>聯(lián)系人：</span>謝進濤</p><p><span>郵箱: </span>267304616@qq.com</p><p><span>電話: </span>15852535713</p><p><span>傳真: </span>0510_86380198</p><p><span>網(wǎng)址: </span></p><p><span>手機: </span>0510-86380198</p><p><span>地址: </span>沙嘴街道光湖路8號</p><p>[當前離線] <a rel="nofollow"> [加為商友] </a><a rel="nofollow"> [發(fā)送信件] </a></p></div></div><div id="s2z9vi7" class="page-proshow02"><p class="title">詳細說明</p><div id="il3v8eq" class="box"><p><p> 分析其原因可能是碘的化合物與染料反應形成具有保護作用的碘化物，碘化物與鋁發(fā)生反應，形成耐水的沉淀物，保證封孔質量；2）在封孔劑中加入鉬酸鹽以及鑭的化合物，能夠生成鉬的氫氧化物及鑭的氫氧化物，生成的氫氧化物能夠將陽極氧化膜的孔隙封閉且在封孔過程中能夠吸附到孔隙中提高鋁合金的抗腐蝕性能；3）在封孔劑中加入磷酸鹽及硅烷偶聯(lián)劑能夠吸附到陽極氧化膜孔隙中，并將其填充封閉，從而減少染料在封孔過程中掉色，提高鋁合金產(chǎn)品的抗鹽霧性能；本發(fā)明通過鉬酸鹽、磷酸鹽，南通無鎳封孔劑研究、碘的化合物、鑭的化合物和硅烷偶聯(lián)劑的配合使用，能夠有效地防止或減少鋁合金陽極氧化膜染色處理后的染料掉色，并提高鋁合金陽極氧化膜的封孔質量及產(chǎn)品的耐腐蝕性能。推薦地，南通無鎳封孔劑研究，所述鉬酸鹽為鉬酸鈉和/或鉬酸銨；所述磷酸鹽為磷酸鈉、磷酸鉀或三聚磷酸鈉中的至少一種；所述碘的化合物為碘化鉀，南通無鎳封孔劑研究、碘化鈉和碘化銨中的至少一種；所述鑭的化合物為氯化鑭和/或氧化鑭；所述硅烷偶聯(lián)劑為γ-(2,3-環(huán)氧丙氧)丙基三甲氧基硅烷、γ-氨丙基三乙氧基硅烷、苯胺甲基三甲氧基硅烷和脲丙基三乙氧基硅烷中的至少一種。推薦地，所述封孔劑還包括苯磺酸鹽。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="南通無鎳封孔劑研究" src="https://tyunfile.71360.com/UploadFile/xtsbsd1/637262913937138672/5901259.png"></div><p> 低pH值有利于Al2O3與F-反應，生成AlF63-、\、Al(OH)F53-、、Al(OH)2F43-.。其含量達到一定值時，離子間發(fā)生締合、水解和濃縮，轉化為穩(wěn)定相絡合氟化鋁Al2(OH)3F3,。在氧化膜微孔中，Al2(OH)3F3是封孔物質；在鋁合金表面，Al2(OH)3F3是粉霜；在槽液中，Al2(OH)3F3是渾濁物。所以槽液溶鋁量太大，鋁合金易上粉，槽液易渾濁死槽。緩蝕劑的添加，正是為了保護氧化膜不上粉，降低溶鋁量，延長槽液使用壽命。按實驗結果，有機醇緩蝕劑的濃度區(qū)間為1-3g/L。（6）螯合劑濃度對封孔質量的影響本發(fā)明螯合劑選用乙酸系(如三乙醇胺、乙二胺四乙酸等),磷酸系(如三聚磷酸鈉、焦磷酸鈉、偏磷酸鈉、氨基三甲叉磷酸（ATMP）等)和磷酸基羧酸系（如膦酰基丁烷三羧酸（PBTCA）等），用其強大的螯合鍵能，穩(wěn)定Ti4+和Al3+,確保槽液不渾濁，鋁合金不上粉。按（2）（5）式，pH升高時，容易生成Ti(OH)4和Al2(OH)3F3。這些物質，若生成在氧化膜微孔，即為封孔物質；若生成在鋁合金表面，即為粉；若生成在槽液中，即為渾濁物。螯合劑的加入，提高了Ti(OH)4和Al2(OH)3F3的生成門檻。螯合劑的用量要特別注意，濃度太高，螯合鍵不好打開，封孔能力急劇下降。實驗表明，恰當?shù)尿蟿舛葹?-3g/L。。</p><div style="width:100%;text-align: center;"><img style="max-width: 640px; max-height: 320px;" alt="南通無鎳封孔劑研究" src="https://tyunfile.71360.com/UploadFile/xtsbsd1/637262913996914063/9599976.png"></div><p> 抗壞血酸，十六烷基三甲溴化銨(ctab，國藥集團工業(yè)股份有限公司)，氟化銨(nh4f，國藥集團工業(yè)股份有限公司)，正硅酸乙酯(teos，國藥集團工業(yè)股份有限公司)，通過該制備方法合成載se量30wt.％的se-msns。其具體步驟為：稱取、，隨后加入250ml去離子水，反應溫度80℃，充分攪拌1h，轉子轉速控制在200～300rpm；反應1h后，向反應體系中逐滴加入，繼續(xù)反應1h后，冷卻至室溫將樣品離心，將沉淀冷凍干燥得到的白色粉末置于馬弗爐600℃煅燒5h，除去msns中的ctab；稱取，得到濃度為；攪拌條件下將，轉速控制在200～300rpm，溫度控制在21～25℃，時間保持在8h，10000～10500rpm離心后用去離子水和無水乙醇洗滌三次，冷凍干燥離心后的沉淀產(chǎn)物，得到擴孔的msns。稱取，記為a液；稱取，記為b液；充分攪拌(轉速控制在200～300rpm)使其全部溶于去離子水中；超聲條件下，將b液用注射器迅速滴加到a液，待反應液出現(xiàn)紅色物質后繼續(xù)反應15min，記為c液；將c液冷凍干燥，然后將產(chǎn)物置于馬弗爐235℃煅燒5h，用去離子洗滌至廢液為澄清透明，將沉淀冷凍干燥得到紅色粉末30wt.％se-msns。實施例2通過該制備方法合成載硒量20wt.％的se-msns。其具體步驟為：擴孔的msns制備方法與實施例1相同。</p></p><br /><p>文章來源地址: http://www.cdcfah.com/cp/436932.html</p></div></div></div></div></div><div id="bp332he" class="page-right twoColRt"><div id="kjtpwn8" class="box01 margin10 clearfix"><h3><a href="http://www.cdcfah.com/cp/">猜你喜歡</a></h3><div id="mgn8z32" class="recomPic likePro"><a href="http://www.cdcfah.com/cp/814588.html"><div><img 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